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poly(butyleneoxide)

terathane(R) 1400

CAS: 25190-06-1

Molecular Formula: C16H33O5X2

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poly(butyleneoxide) - Names and Identifiers

Name terathane(R) 1400
Synonyms PTMG
b2000
PTMEG
polifurit
hiprenemc532
Terathane 1400
terathane(R) 1400
poly(butyleneoxide)
Poly(tetrahydrofuran)
(2S)-2-butoxybutan-1-ol
glycols,polytetramethylene
poly(oxy-1,4-butylene)glycol
alpha-hydro-omega-hydroxy-poly(oxy-4-butanediyl)
terathane 2000 polyether glycol (poly-tetrahydrof
4-butanediyl),.alpha.-hydro-.omega.-hydroxy-poly(oxy-1
CAS 25190-06-1
EINECS 607-637-9
InChI InChI=1/C8H18O2/c1-3-5-6-10-8(4-2)7-9/h8-9H,3-7H2,1-2H3/t8-/m0/s1

poly(butyleneoxide) - Physico-chemical Properties

Molecular FormulaC16H33O5X2
Molar Mass305.43
Density1g/mLat 25°C
Melting Point33-36°C
Boling Point195.7°C at 760 mmHg
Flash Point>230°F
Vapor Presure<0.01 mm Hg ( 25 °C)
Specific Gravity0.961
PH7 (H2O, 20℃)Aqueous solution
Storage ConditionStore below +30°C.
Refractive Indexn20/D 1.465
Physical and Chemical PropertiesPolytetrahydrofuran is a white waxy solid that dissolves readily in alcohols, esters, ketones, aromatic hydrocarbons, and chlorinated hydrocarbons, and is insoluble in ester hydrocarbons and water, and becomes a transparent liquid when the temperature exceeds room temperature.

poly(butyleneoxide) - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk Codes36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
WGK Germany1
RTECSMD0916000
HS Code3907 20 20
ToxicityLD50 orally in Rabbit: > 5000 mg/kg

poly(butyleneoxide) - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
application polytetrahydrofuran, as an important chemical raw material, is mainly used to prepare spandex in the field of chemical fiber and in the field of non-fiber for the preparation of elastomers, adhesives, coatings, sealants and other fields. polyurethane products prepared by it are wear-resistant, chemical-resistant, and have good flexibility and resilience. At present, the top three applications of polytetrahydrofuran abroad are polyurethane elastic fiber (49%), polyurethane elastomer (36%) and ester ether copolymer elastomer (15%).
Preparation Using perchloric acid as a catalyst and anhydride as a capping agent, the polymerization reaction is carried out at a temperature lower than 25°C, and then sodium hydroxide solution is added to terminate the reaction, After distillation to remove unreacted tetrahydrofuran and water, the polymer is washed out of salt, and the polytetrahydrofuran ether glycol diester is obtained by distillation and dehydration, and then methanol is added for transesterification reaction, then add water to neutralize, evaporate excess methanol and methyl ester to obtain crude products, and finally dehydrate again to obtain pure polytetrahydrofuran.
use used in the production of TPU, CPU, PU resin, PU slurry, polyurethane elastomer, etc.
PTMEG is one of the important raw materials for the production of spandex and polyamino acid elastomer. it is used as a soft segment in urethane and can provide polyurethane products with good hydrolysis resistance, low temperature resistance and dynamic properties. It can also be used as the main raw material for elastomer products, synthetic leather resins, and elastic fibers (spandex).
Last Update:2024-04-10 22:29:15
poly(butyleneoxide)
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