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n-tridecyl-2,6-dimethylmorpholine

tridemorph

CAS: 24602-86-6;81412-43-3

Molecular Formula: C19H39NO

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n-tridecyl-2,6-dimethylmorpholine - Names and Identifiers

Name tridemorph
Synonyms e-236
Calixin
CALIXIN
tridemorph
TRIDEMORPH
Tridemorph(ISO)
n-tridecyl-2,6-dimethylmorpholin
2,6-DIMETHYL 4-TRIDECYLMORPHOLINE
2,6-Dimethyl-4-tridecylmorpholine
n-tridecyl-2,6-dimethylmorpholine
2,6-dimethyl-4-tridecyl-morpholin
CAS 24602-86-6
81412-43-3
EINECS 246-347-3
InChI InChI=1/C19H39NO/c1-4-5-6-7-8-9-10-11-12-13-14-15-20-16-18(2)21-19(3)17-20/h18-19H,4-17H2,1-3H3

n-tridecyl-2,6-dimethylmorpholine - Physico-chemical Properties

Molecular FormulaC19H39NO
Molar Mass297.52
Density0.8600
Boling Pointbp0.7 130-133°; bp1.3 139-142°
Flash Point109.5°C
Vapor Presure1.04E-05mmHg at 25°C
Appearanceneat
pKa7.63±0.10(Predicted)
Storage Condition0-6°C
Refractive IndexnD25 1.4568
Physical and Chemical PropertiesPure product is colorless oily liquid, slightly ammonia flavor. B. p.134 °c/66.65, 130-131 °c/22.7, vapor pressure 1.27 x 10-2Pa (20 °c). Soluble in acetone, chloroform, benzene, ethanol and other organic solvents, room temperature in water solubility of 0.01%. Storage Stability at room temperature.

n-tridecyl-2,6-dimethylmorpholine - Risk and Safety

Risk CodesR20/22 - Harmful by inhalation and if swallowed.
R38 - Irritating to the skin
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R61 - May cause harm to the unborn child
Safety DescriptionS45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S53 - Avoid exposure - obtain special instructions before use.
S60 - This material and its container must be disposed of as hazardous waste.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
UN IDsUN 3082
WGK Germany3
RTECSQE2705000
HS Code29349990
Hazard Class6.1(b)
Packing GroupIII

n-tridecyl-2,6-dimethylmorpholine - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
toxicity acute oral LD50 in rats> 1000 mg/kg(558 mg/kg, crude oil) and acute oral LD50750mg in rabbits/kg. Acute percutaneous LD50>4000mg/kg, acute inhalation LC504.5mg/L in rats. The subchronic non-action dose was 50mg/kg in rats and 800mg/kg in dogs. The chronic non-effect dose was 80mg/kg in rats and 90mg/kg in mice. Rats were placed in 13 morpholine saturated air, and no death was found after 8 hours. Large dose (220L/kg) has teratogenic and reproductive toxicity, low dose (24L/kg) has no effect. No mutagenic and carcinogenic effects. Add 360kg of dichlorodiisopropyl ether, synthesize 120kg of C11 ~ C13 fatty amine, 140kg of liquid alkali and 100kg of water, react at 95 ℃ for 4h under stirring, continue to raise the temperature to 110 ℃ for 1h, and the reaction ends. The water phase is sent to the three wastes for treatment, the oil phase is distilled, the negative pressure is stable at 2.67kPa, the reflux ratio is 1:1~2:1, the top temperature of the tower is 83~86 ℃ for the fraction to recover ether, the 100~160 ℃ fraction to recover amine, and the 160~200 ℃ fraction to obtain 13 morpholine. The yield of amine is ≥ 80%, and the content is ≥ 95%.
use morpholine fungicides, which have both protective, therapeutic and systemic effects, have long residual effects and have no phytotoxicity to crops. they are used to prevent and control powdery mildew of barley and wheat, leaf rust and stripe rust of wheat, powdery mildew of cucumber, potato, rubber and pea.
Used as a pharmaceutical intermediate
Production method It is made of N,N-bis (β-hydroxypropyl) thirteen amine in the presence of sulfuric acid and dehydration at 160 ℃.
category pesticide
toxicity classification poisoning
acute toxicity oral-rat LD50: 650 mg/kg; Oral-mouse LD50: 1560 mg/kg
flammability hazard characteristics combustion produces toxic nitrogen oxide gas
storage and transportation characteristics warehouse ventilation and low temperature drying; separate from food raw materials storage and transportation
fire extinguishing agent dry powder, foam, sand
Last Update：2024-04-09 21:04:16
n-tridecyl-2,6-dimethylmorpholine
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SHANGHAI ACMEC BIOCHEMICAL TECHNOLOGY CO., LTD.
Spot supply
Product Name: Tridemorph Visit Supplier Webpage Request for quotation
CAS: 24602-86-6
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922 Click to send a QQ message
Wechat: 18621343501
WhatsApp: +86-18621343501
Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: tridemorph Request for quotation
CAS: 24602-86-6
Tel: 0086-551-65418684
Email: sales@tnjchem.com
　　　　 info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840 Click to send a QQ message
Wechat: 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Hubei Marvel-Bio Medicine
Product Name: Tridemorph Request for quotation
CAS: 24602-86-6
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Email: 2295636945@qq.com
Mobile: 15387132319
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View History
n-tridecyl-2,6-dimethylmorpholine
十二烷基2-(二甲基氨基)丙酸酯盐酸盐
2-碘-4,6-二甲基苯胺
1,2-DIPALMITOYL-GLYCERO-2-PHOSPHOCHOLINE MONOHYDRATE
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7BETA-羟基蟾毒灵
2-[2-(methylthio)benzimidazol-1-yl]propionic acid
4-[(2,6-DIMORPHOLINOPYRIMIDIN-4-YL)CARBONYL]MORPHOLINE
二氟甲氧基苯
CERAMIDE 1
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