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2,6-DIBROMOPHENOL

2,6-Dibromophenol

CAS: 608-33-3

Molecular Formula: C6H4Br2O

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2,6-DIBROMOPHENOL - Names and Identifiers

Name 2,6-Dibromophenol
Synonyms 2,6-DIBROMOPHENOL
2,6-dibromo-pheno
2,6-Dibromophenol
2,6-Dibromo Phenol
Dibromophenol, 2,6-
Phenol, 2,6-dibromo-
CAS 608-33-3
EINECS 210-161-0
InChI InChI=1/C6H4Br2O/c7-4-2-1-3-5(8)6(4)9/h1-3,9H
InChIKey SSIZLKDLDKIHEV-UHFFFAOYSA-N

2,6-DIBROMOPHENOL - Physico-chemical Properties

Molecular FormulaC6H4Br2O
Molar Mass251.9
Density1.8854 (rough estimate)
Melting Point53-56 °C (lit.)
Boling Point255-256 °C/740 mmHg (lit.)
Flash Point255-256°C
Water SolubilitySoluble in ethanol and ether. Slightly soluble in water.
Vapor Presure0.009mmHg at 25°C
AppearanceWhite crystal
ColorWhite
Maximum wavelength(λmax)['286nm(EtOH)(lit.)']
BRN2043614
pKa6.89±0.10(Predicted)
Storage Conditionroom temp
Refractive Index1.5380 (estimate)
MDLMFCD00002152
Physical and Chemical Properties

Boiling Point: 255-256 (p = 740 torr)

Melting Point: 54 - 57

2,6-DIBROMOPHENOL - Risk and Safety

Risk CodesR20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38 - Irritating to eyes, respiratory system and skin.
R22 - Harmful if swallowed
Safety DescriptionS28 - After contact with skin, wash immediately with plenty of soap-suds.
S36/37 - Wear suitable protective clothing and gloves.
S37/39 - Wear suitable gloves and eye/face protection
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
UN IDsUN 2811 6.1/PG 3
WGK Germany3
TSCAYes
HS Code29081000
Hazard NoteIrritant
Hazard Class6.1(b)
Packing GroupIII

2,6-DIBROMOPHENOL - Reference Information

NIST chemical information information provided by: webbook.nist.gov (external link)
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
biological activity 2, 6-dibromophanol is an endogenous metabolite.
Use organic synthesis, preparation of 3,4, 5-trimethoxybenzaldehyde, etc.
production method is obtained by sulfonation, Bromination and hydrolysis of phenol. 98% sulfuric acid was added dropwise to phenol at 44-50 ℃, heated to 100 ℃ for 3H, ice water was added to dissolve solid, then bromine was added dropwise at 20 ℃, and chlorine gas was introduced, after adding sodium bisulfite to react for 30min under stirring, filtering, the filter cake is tribromide, the filtrate is passed through superheated steam distillation, and the initial distillate (containing tribromide and one bromide) is discarded, the distillate was collected at an internal temperature of 155 ° C. Or higher, and crystals were precipitated by cooling to obtain a finished product. The yield was 80%.
toxic substance data information provided by: pubchem.ncbi.nlm.nih.gov (external link)
Last Update:2024-04-09 21:04:16
2,6-DIBROMOPHENOL
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2,6-DIBROMOPHENOL
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