Bis(2-cyanoethyl)ether
2-Cyanoethyl ether
CAS: 1656-48-0
Molecular Formula: C6H8N2O
Bis(2-cyanoethyl)ether - Names and Identifiers
Bis(2-cyanoethyl)ether - Physico-chemical Properties
| Molecular Formula | C6H8N2O |
| Molar Mass | 124.14 |
| Density | 1.043 g/mL at 25 °C (lit.) |
| Melting Point | -26 °C |
| Boling Point | 110-112 °C/0.5 mmHg (lit.) |
| Flash Point | >230°F |
| Water Solubility | Soluble in water |
| Vapor Presure | 0.000488mmHg at 25°C |
| Appearance | clear liquid |
| Color | Colorless liquid |
| BRN | 1746454 |
| Refractive Index | n20/D 1.441(lit.) |
| Physical and Chemical Properties | Colorless or pale yellow oily liquid. Boiling point 167-174 ℃,137-138 ℃(0.267kPa), relative density 1.043, refractive index 1.4400. Soluble in ethanol, acetone, chloroform, insoluble in water, carbon tetrachloride. |
Bis(2-cyanoethyl)ether - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | R36/37/38 - Irritating to eyes, respiratory system and skin. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. |
| Safety Description | S23 - Do not breathe vapour. S24/25 - Avoid contact with skin and eyes. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| WGK Germany | 2 |
| RTECS | UG4200000 |
| TSCA | Yes |
| Toxicity | LD50 orl-rat: 2830 mg/kg AMIHBC 10,61,54 |
Bis(2-cyanoethyl)ether - Reference Information
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Use | for organic synthesis. |
| production method | the strongly basic resin with quaternary ammonium salt deposited on polystyrene was added to water and heated to 45 °c, acrylonitrile was slowly added dropwise under the liquid level, and the reaction was completed at 45-47 ° C. For 4-5H. The reactants were distilled off from excess acrylonitrile under atmospheric pressure, and then distilled under reduced pressure to collect the 119-120 ° C. (0.13kPa) fraction to obtain the product 2-cyanoethyl ether. Yield 77%. |
| category | toxic substances |
| Acute toxicity | oral-rat LD50: 2830 mg/kg |
| stimulation data | Skin-rabbits 500 mg/24 h mild; eye-rabbit 500 mg/24 h mild |
| flammability hazard characteristics | open flame flammable; High heat releases toxic nitrogen oxides and cyanide gases |
| storage and transportation characteristics | The warehouse is ventilated and dried at low temperature, separate storage of food additives |
| extinguishing agent | dry powder, foam, carbon dioxide, sand, anti-soluble foam. The acid-base extinguishing agent is not allowed. |
Last Update：2024-04-09 21:04:16
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View History
Bis(2-cyanoethyl)ether
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