过钌酸四丙胺盐(TPAP)
Tetra-n-propylammonium perruthenate(VII)
CAS: 114615-82-6
Molecular Formula: C12H28NO4Ru
过钌酸四丙胺盐(TPAP) - Names and Identifiers
| Name | Tetra-n-propylammonium perruthenate(VII) |
| Synonyms | TPAP tetrapropylammonium oxido-trioxo-ruthenium TerapropylaMMoniuMperruthenate Tetrapropylammonium perruthenate TETRAPROPYLAMMONIUM PERRUTHENATE TETRA-N-PROPYLAMMONIUM PERRUTHENATE Tetrapropylammonium tetraoxoruthenate Tetra-n-propylammonium perruthenate(VII) TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII) 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoru |
| CAS | 114615-82-6 |
| EINECS | 628-415-8 |
| InChI | InChI=1/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;/rC12H28N.O4Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;1-5(2,3)4/h5-12H2,1-4H3;/q+1;-1 |
| InChIKey | NQSIKKSFBQCBSI-UHFFFAOYSA-N |
过钌酸四丙胺盐(TPAP) - Physico-chemical Properties
| Molecular Formula | C12H28NO4Ru |
| Molar Mass | 351.43 |
| Melting Point | ~160 °C (dec.) (lit.) |
| Water Solubility | Insoluble in water. |
| Solubility | Methanol (Slightly) |
| Appearance | crystal |
| Color | green |
| Storage Condition | Inert atmosphere,2-8°C |
| Stability | store cold |
| Sensitive | Hygroscopic |
| MDL | MFCD00074914 |
| Use | Soluble, non-volatile, air-stable, mild catalysts that can be used with appropriate co-oxidants in stoichiometric terms or as catalytic applications. An oxidant used to convert N,N′-dihydroxyimidazoline into nitroxide radicals. Oxidation of hydroxyl-substituted tri-n-butylammonium trifluoroborate to aldehydes and ketones without? concomitant cleavage of the carbon-boron bond. |
过钌酸四丙胺盐(TPAP) - Risk and Safety
| Risk Codes | R5 - Heating may cause an explosion R8 - Contact with combustible material may cause fire R36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S17 - Keep away from combustible material. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. |
| UN IDs | UN 1479 5.1/PG 2 |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 3-10 |
| HS Code | 28439000 |
| Hazard Class | 5.1 |
| Packing Group | III |
过钌酸四丙胺盐(TPAP) - Reference Information
| use | soluble, non-volatile, air-stable mild catalyst, can be used with appropriate co-oxidizer according to stoichiometry or as catalytic use. An oxidant used to convert N,N′-dihydroxyimidazoline into nitroxide radicals. Oxidation of hydroxyl-substituted tri-n-butylammonium trifluoroborate to aldehydes and ketones without? concomitant cleavage of the carbon-boron bond. |
Last Update：2024-04-10 22:29:15
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View History
过钌酸四丙胺盐(TPAP)
4-戊基苯甲酸 4-[(4-丙基苯甲酰基)氧基]苯基酯
C-TYPE NATRIURETIC PEPTIDE-53
Chrysin 6-C-glucoside 8-C-arabinoside
METHYL 3-[(CYCLOPROPYLCARBONYL)AMINO]-4-(4-PHENYLPIPERAZINO)BENZENECARBOXYLATE
Vinclozolin M2 (M2)
D-ALPHA-TOCOPHEROL QUINONE
4-丁基苯甲酸 4-[(4-戊基苯甲酰基)氧基]苯基酯
2,4-二氢-2-[4-[(2-羟基乙基)磺酰基]苯基]-5-甲基-3H-吡唑-3-酮
1-丙基丁基溴化锌, 0.5M THF溶液, 氩气下用可重封的 CHEMSEAL 瓶包装
4-戊基苯甲酸 4-[(4-丙基苯甲酰基)氧基]苯基酯
C-TYPE NATRIURETIC PEPTIDE-53
Chrysin 6-C-glucoside 8-C-arabinoside
METHYL 3-[(CYCLOPROPYLCARBONYL)AMINO]-4-(4-PHENYLPIPERAZINO)BENZENECARBOXYLATE
Vinclozolin M2 (M2)
D-ALPHA-TOCOPHEROL QUINONE
4-丁基苯甲酸 4-[(4-戊基苯甲酰基)氧基]苯基酯
2,4-二氢-2-[4-[(2-羟基乙基)磺酰基]苯基]-5-甲基-3H-吡唑-3-酮
1-丙基丁基溴化锌, 0.5M THF溶液, 氩气下用可重封的 CHEMSEAL 瓶包装