二(乙腈)(1,5-环辛二烯)四氟硼酸铑(I)

二(乙腈)(1,5-环辛二烯)四氟硼酸铑(I) - Names and Identifiers

Name	Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Synonyms	5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE Bis(acetonitrile)(cyclooctadiene)rhodium tetrafluoroborate Bis(acetonitrile)cycloocta-1,5-dienerhodium tetrafluoroborate Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluorob... Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(1+) tetrafluoroborate acetonitrile,(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate
CAS	32679-02-0

二(乙腈)(1,5-环辛二烯)四氟硼酸铑(I) - Physico-chemical Properties

Molecular Formula	C12H14BF4N2Rh
Molar Mass	375.97
Appearance	solid
Color	yellow
Storage Condition	under inert gas (nitrogen or Argon) at 2-8°C
Sensitive	Air Sensitive

二(乙腈)(1,5-环辛二烯)四氟硼酸铑(I) - Risk and Safety

Hazard Symbols	Xi - Irritant
Risk Codes	36/37/38 - Irritating to eyes, respiratory system and skin.
Safety Description	26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany	3
TSCA	No

二(乙腈)(1,5-环辛二烯)四氟硼酸铑(I) - Introduction

Bis(acetonitril) (1,5-cycloctadiene) rhodium(I) tetrafluoroborate is a chemical complex with the formula [Rh(C2H3N)2(C8H12)] Bf4. The following is a description of some properties, uses, preparation and safety information about this compound:

Nature:
- Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a yellow solid.
-It is insoluble in water, but soluble in organic solvents such as ethanol, acetone and dimethylformamide.
-It is stable to light and air, and has high stability at room temperature.

Use:
- Bis(acetonitril)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is an important catalyst, which is widely used in a variety of organic synthesis reactions. For example, it is commonly used in hydrogenation, reduction and carbonylation reactions.
-It also has applications for asymmetric catalytic reactions.

Method:
-Generally, the method of preparing Bis(acetonitril) (1,5-cycloctadiene) rhodium(I) tetra fluoroborate is to combine rhodium pentachloride with an excess of 1, reaction of 5-cyclooctadiene and acetonitrile.
-After the reaction is completed, the obtained product can be extracted by crystallization or other purification methods.

Safety Information:
- Bis(acetonitril)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a toxic compound that needs to be operated under closed laboratory conditions.
-Avoid direct contact with skin and eyes when handling this compound.
-When using or storing, avoid contact with flammable materials, and keep away from high temperature and open fire.
-Use personal protective equipment such as protective gloves and safety glasses when performing operations.

Last Update：2024-04-10 22:29:15