vinylfluoride(vf)
VINYL FLUORIDE
CAS: 75-02-5
Molecular Formula: C2H3F
vinylfluoride(vf) - Names and Identifiers
| Name | VINYL FLUORIDE |
| Synonyms | vinyl inhibied FLUOROETHYLENE VINYL FLUORIDE vinylfluoride(vf) vinylfluoride,inhibited Fluoroethene~Fluoroethylene Vinylfluorideinhibitedwithdlimonene |
| CAS | 75-02-5 |
| EINECS | 200-832-6 |
vinylfluoride(vf) - Physico-chemical Properties
| Molecular Formula | C2H3F |
| Molar Mass | 46.04 |
| Density | 0,615 g/cm3 |
| Melting Point | -160,5°C |
| Boling Point | -72°C |
| Refractive Index | 1.34 |
| Physical and Chemical Properties | Chemical properties: colorless combustible gas at room temperature and pressure. It has an ether flavor. Freezing point -162 ℃, boiling point -72.2 ℃(-15 ℃,-66 ℃), relative density 0.835(-72.2/4 ℃), critical temperature 54.7 ℃, monitoring pressure 5.1MPa, critical density 0.320g/cm3. Can be added with bromine hydrogen halide. It is also easy to copolymerize with olefins, fluoroolefins, styrene, etc. The auto-ignition limit is 2.6%-27.1% (volume). Soluble in acetone, ethanol. The burning flame is green and easy to aggregate. |
| Use | Mainly used for the production of poly (vinyl fluoride), poly (vinyl fluoride) is the lowest fluorine content in fluorine plastic, the relative density of the smallest products. It is also used in the synthesis of other resins. It can also be used as chemical anti-corrosion coating, lining, capacitor film, food packaging container surface flour coating, etc. |
vinylfluoride(vf) - Risk and Safety
| Hazard Symbols | F - Flammable |
| Risk Codes | R12 - Extremely Flammable R40 - Limited evidence of a carcinogenic effect |
| Safety Description | S9 - Keep container in a well-ventilated place. S16 - Keep away from sources of ignition. S23 - Do not breathe vapour. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| UN IDs | 1860 |
| Hazard Class | 2.1 |
vinylfluoride(vf) - Upstream Downstream Industry
vinylfluoride(vf) - Nature
| (IARC) Carcinogen Classification | 2A (Vol. Sup 7, 63, 97) 2008 |
| EPA chemical information | Vinyl fluoride (75-02-5) |
Last Update：2024-04-10 22:29:15
vinylfluoride(vf) - Security information
| toxic substance data | 75-02-5(Hazardous Substances Data) |
Last Update：2024-04-10 22:29:15
vinylfluoride(vf) - Uses and synthesis methods
production method
It is obtained by the reaction of acetylene and anhydrous hydrogen fluoride. After being purified by potassium dichromate, the acetylene dried by solid alkali and silica gel is mixed with anhydrous hydrogen fluoride, and poured into a reaction tube with aluminum fluoride catalyst to maintain the reaction at 250-350 ℃ (the reaction temperature increases with the decrease of catalyst activity). The gas flowing out of the reactor is cooled and washed with water to remove unreacted hydrogen fluoride, and then passed through the heated copper oxide catalyst layer to remove unreacted acetylene. At this time, in addition to fluoroethylene, the gas product also contains difluoroethane and trace amounts of acetylene, ethylene and non-condensable gases. Another method is to catalyze the addition of vinyl chloride and hydrogen fluoride to obtain 1, 1-fluorochloroethane, and then dehydrochlorinate to obtain fluoroethylene.
category
Compressed gas and liquefied gas
toxicity classification
low toxicity
acute toxicity
inhalation-rat LC 80000 PPM/12.5 h
explosive hazard characteristics
Explosive mixing with air
flammability hazard characteristics
Flammable; decomposes toxic hydrogen fluoride gas when heated
storage and transportation features
The warehouse is ventilated and dry at low temperature; stored separately from the oxidant
fire extinguishing agent
Water
Last Update：2024-04-09 19:04:55
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vinylfluoride(vf)
氯五(甲胺)二氯化钴
5-二溴氯苯
(2,4-二氟苯基)-(4-哌啶基)甲酮肟盐酸盐
11H-全氟十一酸乙酯
2-(2-(2-甲氧基乙氧基)乙氧基)丙酸
4- 羟基 -2- 甲基 -2H-1,2- 苯并噻嗪 -3- 羧酸乙酯 1,1- 二氧化物
氯五(甲胺)二氯化钴
5-二溴氯苯
(2,4-二氟苯基)-(4-哌啶基)甲酮肟盐酸盐
11H-全氟十一酸乙酯
2-(2-(2-甲氧基乙氧基)乙氧基)丙酸
4- 羟基 -2- 甲基 -2H-1,2- 苯并噻嗪 -3- 羧酸乙酯 1,1- 二氧化物
Raw Materials for vinylfluoride(vf)
Sodium hydroxide
Potassium dichromate
CHLOROETHANE
Cupric oxide
2-IODO-1,1-DIFLUOROETHANE
2,3,3,3-TETRAFLUOROPROPENE
Potassium dichromate
CHLOROETHANE
Cupric oxide
2-IODO-1,1-DIFLUOROETHANE
2,3,3,3-TETRAFLUOROPROPENE
Downstream Products for vinylfluoride(vf)
potassium ω-hydroperfluoyope largonate
trans-1-Fluoro-1-propene
2-CHLORO-3,3,3-TRIFLUOROPROPENE
Trifluoromethane
trans-1-Fluoro-1-propene
2-CHLORO-3,3,3-TRIFLUOROPROPENE
Trifluoromethane