Molecular Formula | C12O12Ru3 |
Molar Mass | 639.33 |
Melting Point | 150 °C |
Solubility | Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. |
Appearance | Orange crystal |
Color | orange |
Storage Condition | Inert atmosphere,Room Temperature |
MDL | MFCD00011209 |
Risk Codes | R11 - Highly Flammable R20 - Harmful by inhalation R2017/11/20 - |
Safety Description | 24/25 - Avoid contact with skin and eyes. |
UN IDs | 1325 |
WGK Germany | 3 |
TSCA | Yes |
HS Code | 28439000 |
Hazard Note | Flammable/Harmful |
Hazard Class | 6.1 |
Packing Group | II |
EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
Application field | The main application fields of tricarthenium dodecacarbonyl are as follows: 1, as a catalyst for silyl acetylene compounds and α,β-The [3 2 1] carbonyl cycloaddition reaction of unsaturated ketones yields α-pyrone in high yield. 2, precursor of carbonyl cluster and hydrogen transfer catalyst. 3, used for the reductive carbonylation of aromatic nitro compounds to form carbamates. 4, the phosphine-stabilized carbonyl cluster has been connected to the oxide carrier. 5, used to obtain improved catalytic effect in the allylation reaction of unactivated olefins by aromatic nitro compounds. |
Use | Precursors of carbonyl groups and H-transfer catalysts. Used for the reductive carbonylation of aromatic nitro complexes to carbamates. |