TRI-TERT-BUTYLPHOSPHINE
tris(1,1-dimethylethyl)phosphine
CAS: 13716-12-6
Molecular Formula: C12H27P
TRI-TERT-BUTYLPHOSPHINE - Names and Identifiers
| Name | tris(1,1-dimethylethyl)phosphine |
| Synonyms | TTBP Tri-tert-butyL TRI-T-BUTYLPHOSPHINE Tri-t-butylphosphine Tri(t-butyl)phosphine Tri-t-butylphosphosphin TRI-TERT-BUTYLPHOSPHINE tri-tert-butylphosphane Tri-tert-butylphosphine TRI-TERT-BUTYL-PHOSPHANE tris(1,1-dimethylethyl)phosphine Phosphine, tris(1,1-dimethylethyl) Phosphine, tris(1,1-dimethylethyl)- |
| CAS | 13716-12-6 |
| EINECS | 237-266-4 |
| InChI | InChI=1/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3 |
| InChIKey | BWHDROKFUHTORW-UHFFFAOYSA-N |
TRI-TERT-BUTYLPHOSPHINE - Physico-chemical Properties
| Molecular Formula | C12H27P |
| Molar Mass | 202.32 |
| Density | 0.861g/mLat 25°C |
| Melting Point | 30-35°C(lit.) |
| Boling Point | 102-103°C13mm Hg(lit.) |
| Flash Point | 1°F |
| Water Solubility | insoluble |
| Vapor Presure | 0.105mmHg at 25°C |
| Appearance | solid |
| Specific Gravity | 0.68 |
| BRN | 1738613 |
| Storage Condition | Flammables area |
| Sensitive | Air & Moisture Sensitive |
TRI-TERT-BUTYLPHOSPHINE - Risk and Safety
| Risk Codes | R17 - Spontaneously flammable in air R34 - Causes burns R67 - Vapors may cause drowsiness and dizziness R65 - Harmful: May cause lung damage if swallowed R63 - Possible risk of harm to the unborn child R48/20 - R11 - Highly Flammable |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S62 - If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S25 - Avoid contact with eyes. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S27 - Take off immediately all contaminated clothing. S16 - Keep away from sources of ignition. |
| UN IDs | UN 2846 4.2/PG 1 |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 10-19-23 |
| HS Code | 29319090 |
| Hazard Class | 4.2 |
| Packing Group | I |
TRI-TERT-BUTYLPHOSPHINE - Reference Information
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| Use | The preferred ligand for the palladium-catalyzed coupling reaction of arylboronic acid with phenyliodoylide of hydroxyquinone. It can also be used with Pd(dba) for the α-arylation of trimethylsilyl enol ethers with aryl halides. |
Last Update：2024-04-10 22:29:15
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View History
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异丙基氯化镁氯化锂混合溶液
BOC-L-3-硝基苯基丙氨酸
4-氯-N-[(4-甲基苯基)磺酰]苯磺胺酰氟,4-氯-N-[(4-甲基苯基)磺酰]苯磺胺酰氟化物 ,4-氯-N-[(4-甲基苯基)磺酰基]苯磺酰亚胺基氟.氟化试剂
替诺福韦R2-M1Z6杂质
乙酸[[2-(FMOC-氨基)乙酰氨基]甲基]酯
粘胶乳香树(PISTACIA LENTISCUS)胶
噻吩-2-羧酸(2,2,4-三甲基-1H-喹啉-6-基)酯
4-羧基苯硼酸丙二醇酯
4-氰基咪唑