Methyl-4-bromobenzoate
Methyl 4-bromobenzoate
CAS: 619-42-1
Molecular Formula: C8H7BrO2
Methyl-4-bromobenzoate - Names and Identifiers
| Name | Methyl 4-bromobenzoate |
| Synonyms | BRBSME RARECHEM AL BF 0075 METHYL 4-BROMOBENZOATE METHYL P-BROMOBENZOATE Methyl 4-bromobenzoate Methyl-4-bromobenzoate 4-bromo-benzoicacimethylester 4-Bromobenzoic Acid Methyl Ester 4-BROMOBENZOIC ACID METHYL ESTER Benzoic acid, 4-bromo-, methyl ester Benzoic acid, p-bromo-, methyl ester |
| CAS | 619-42-1 |
| EINECS | 210-596-6 |
| InChI | InChI=1/C8H7BrO2/c1-11-8(10)6-2-4-7(9)5-3-6/h2-5H,1H3 |
| InChIKey | HANNIMAAZKBBRE-UHFFFAOYSA-N |
Methyl-4-bromobenzoate - Physico-chemical Properties
| Molecular Formula | C8H7BrO2 |
| Molar Mass | 215.04 |
| Density | 1,689 g/cm3 |
| Melting Point | 77-81 °C (lit.) |
| Boling Point | 252.95°C (rough estimate) |
| Flash Point | 112.4°C |
| Water Solubility | Insoluble in water. |
| Solubility | Chloroform (Slightly), Methanol (Slightly) |
| Vapor Presure | 0.0111mmHg at 25°C |
| Appearance | White crystal |
| Color | White |
| Merck | 14,1408 |
| BRN | 2045132 |
| Storage Condition | Sealed in dry,Room Temperature |
| Refractive Index | 1.5500 (estimate) |
| MDL | MFCD00013531 |
Methyl-4-bromobenzoate - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S24/25 - Avoid contact with skin and eyes. |
| WGK Germany | 3 |
| TSCA | Yes |
| HS Code | 29163990 |
Methyl-4-bromobenzoate - Reference Information
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Application | p-bromobenzoic acid methyl ester is also called 4-bromobenzoic acid methyl ester, it has been reported that it can be used to prepare pharmaceutical intermediates such as 4-(4-Methyl phenyl) butyraldehyde, cefaclor A and pemetrexed acid. |
| preparation | a 25 mL reaction flask was filled with a magnet and 1 mmol of 1-bromo-4-(methoxymethyl) benzene (214 mg),15 mg20 mol% AgI/BiVO4 composite and 2 mL water, equipped with an oxygen sphere of 28 cm diameter, equipped with a 16 W white light at the right side of the reaction bottle 10cm, the reaction system was reacted for 15 h under the irradiation of 16 W white light, and the reaction solution was extracted, after combining the organic layers, the mixture was washed three times with saturated brine, dried with anhydrous sodium sulfate, and desolvated under reduced pressure. The residue was treated by column chromatography (ethyl acetate/petroleum ether = 1:10) to obtain methyl p-bromobenzoate, the yield was 88% (188.7 mg). |
Last Update：2024-04-09 02:00:10
Supplier List
Featured Products
Product Name: Methyl 4-bromobenzoate Request for quotationCAS: 619-42-1
Tel: +86-21-56795779
Email: charles7788@worldyachem.com
Mobile: +86-13651600618
QQ: 2850607228
Wechat: +8613651600618
WhatsApp: +8613651600618
Product Name: Methyl 4-bromobenzoate Request for quotation
CAS: 619-42-1
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
CAS: 619-42-1
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Spot supply
Product Name: Methyl 4-bromobenzoate Request for quotationCAS: 619-42-1
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Wechat: chemical6666
Spot supply
Product Name: METHYL 4-BROMOBENZOATE Visit Supplier Webpage Request for quotationCAS: 619-42-1
Tel: +86 0571-86722205
Email: sales@chinaskyrun.com
Mobile: +8618958170122
QQ: 2531159185
Wechat: chinaskyrun
Spot supply
Product Name: Methyl 4-bromobenzoate Visit Supplier Webpage Request for quotationCAS: 619-42-1
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
Spot supply
Product Name: Methyl 4-bromobenzoate Visit Supplier Webpage Request for quotationCAS: 619-42-1
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Spot supply
Product Name: Methyl 4-Bromobenzoate Visit Supplier Webpage Request for quotationCAS: 619-42-1
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Featured Products
Product Name: Methyl 4-bromobenzoate Request for quotationCAS: 619-42-1
Tel: +86-21-56795779
Email: charles7788@worldyachem.com
Mobile: +86-13651600618
QQ: 2850607228
Wechat: +8613651600618
WhatsApp: +8613651600618
Product Name: Methyl 4-bromobenzoate Request for quotation
CAS: 619-42-1
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
CAS: 619-42-1
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Spot supply
Product Name: Methyl 4-bromobenzoate Request for quotationCAS: 619-42-1
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Wechat: chemical6666
Spot supply
Product Name: METHYL 4-BROMOBENZOATE Visit Supplier Webpage Request for quotationCAS: 619-42-1
Tel: +86 0571-86722205
Email: sales@chinaskyrun.com
Mobile: +8618958170122
QQ: 2531159185
Wechat: chinaskyrun
Spot supply
Product Name: Methyl 4-bromobenzoate Visit Supplier Webpage Request for quotationCAS: 619-42-1
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
Spot supply
Product Name: Methyl 4-bromobenzoate Visit Supplier Webpage Request for quotationCAS: 619-42-1
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Spot supply
Product Name: Methyl 4-Bromobenzoate Visit Supplier Webpage Request for quotationCAS: 619-42-1
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
View History
Methyl-4-bromobenzoate
2-氯-N-[4-(4-苯基苯基)-2-噻唑基]乙酰胺
MONALIDE MIXTURE OF ISOMERS, PESTANAL
8-Azabicyclo[3.2.1]octan-3-one hydrochloride
GDC-0980 (RG7422)
5-氟-3-氮杂双环[3.1.1]庚烷-1-甲酸盐酸盐
GEOGRAPHUTOXIN II (GTXII)
p-Dimethylaminobenzoic acid 2-ethylhexyl ester
TERBUFOS-SULFOXIDE PESTANAL, 100 MG
4-ISO-PROPYLOXYBENZOIC ACID
2-氯-N-[4-(4-苯基苯基)-2-噻唑基]乙酰胺
MONALIDE MIXTURE OF ISOMERS, PESTANAL
8-Azabicyclo[3.2.1]octan-3-one hydrochloride
GDC-0980 (RG7422)
5-氟-3-氮杂双环[3.1.1]庚烷-1-甲酸盐酸盐
GEOGRAPHUTOXIN II (GTXII)
p-Dimethylaminobenzoic acid 2-ethylhexyl ester
TERBUFOS-SULFOXIDE PESTANAL, 100 MG
4-ISO-PROPYLOXYBENZOIC ACID