Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II)
Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II)
CAS: 329735-79-7
Molecular Formula: C30H50O4Ru4*
Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) - Names and Identifiers
Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) - Physico-chemical Properties
| Molecular Formula | C30H50O4Ru4* |
| Molar Mass | 575.79 |
| Melting Point | 187-190°C |
| Boling Point | 220°C |
| Appearance | crystal |
| Color | yellow-orange microcrystal |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
| Sensitive | 4: no reaction with water under neutral conditions |
Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| TSCA | No |
Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) - Introduction
Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cycloketadiene) ruthenium(II) is a transition metal complex with the formula Ru(COD)(TMHD)2, where COD means 1,5-cyclooctadiene and TMHD means 2,2,6,6-tetramethyl-3,5-dioxanone. The following is a description of its nature, use, preparation and safety information:
Nature:
- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclootadiene) ruthenium(II) is a solid yellow crystal.
-It is stable at room temperature, but it will decompose when heated.
-Soluble in common organic solvents such as ethanol and dimethylformamide.
Use:
- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) is commonly used as a catalyst in organic synthesis.
-It can be applied to the activation reaction of inert bonds, asymmetric catalysis and hydrogen transfer reactions.
-This complex can also be used to prepare other ruthenium complexes with catalytic activity.
Preparation Method:
- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) can be obtained by reacting ruthenate with 2,2,6,6-tetramethyl-3,5-heptadione and then with 1,5-cyclooctadiene.
Safety Information:
-specific hazard and safety information of Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) may require reference to relevant chemical substance safety information.
-When handling this substance, you need to pay attention to prevent contact with skin and eyes, and avoid inhaling its dust or gas.
-When using or handling the substance, follow relevant laboratory safety procedures and personal protective measures.
Nature:
- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclootadiene) ruthenium(II) is a solid yellow crystal.
-It is stable at room temperature, but it will decompose when heated.
-Soluble in common organic solvents such as ethanol and dimethylformamide.
Use:
- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) is commonly used as a catalyst in organic synthesis.
-It can be applied to the activation reaction of inert bonds, asymmetric catalysis and hydrogen transfer reactions.
-This complex can also be used to prepare other ruthenium complexes with catalytic activity.
Preparation Method:
- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) can be obtained by reacting ruthenate with 2,2,6,6-tetramethyl-3,5-heptadione and then with 1,5-cyclooctadiene.
Safety Information:
-specific hazard and safety information of Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) may require reference to relevant chemical substance safety information.
-When handling this substance, you need to pay attention to prevent contact with skin and eyes, and avoid inhaling its dust or gas.
-When using or handling the substance, follow relevant laboratory safety procedures and personal protective measures.
Last Update：2024-04-10 22:29:15
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Product Name: Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) Visit Supplier Webpage Request for quotationCAS: 329735-79-7
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Product Name: Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II) Visit Supplier Webpage Request for quotationCAS: 329735-79-7
Tel: +86-18821248368
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Product Name: BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)(1,5-CYCLOOCTADIENE)RUTHENIUM (II) Visit Supplier Webpage Request for quotation
CAS: 329735-79-7
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View History
Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)(1,5-cyclooctadiene)ruthenium(II)
Phenol, polymer with formaldehyde, sulfomethylated
Cyclopropanecarboxamide, N,2,2,3,3-pentamethyl- (9CI)
Selinexor (KPT-330)
蜡杨梅(MYRICA CERIFERA)果蜡
SODIUM HOUTTUYFONATE
20869-38-9
4-NITRO-5-TRIFLUOROMETHYL-1H-PYRAZOLE
2-环戊基-1-(4-苯氧基苯基)乙-1-胺
2,6-dichlorophenyl 3,4-dichloro-2-methoxybenzenesulfonate
Phenol, polymer with formaldehyde, sulfomethylated
Cyclopropanecarboxamide, N,2,2,3,3-pentamethyl- (9CI)
Selinexor (KPT-330)
蜡杨梅(MYRICA CERIFERA)果蜡
SODIUM HOUTTUYFONATE
20869-38-9
4-NITRO-5-TRIFLUOROMETHYL-1H-PYRAZOLE
2-环戊基-1-(4-苯氧基苯基)乙-1-胺
2,6-dichlorophenyl 3,4-dichloro-2-methoxybenzenesulfonate