944451-25-6 - Names and Identifiers
Name | Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-xylbinap)]Cl
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Synonyms | [RuCl(p-cymene)((S)-xylbinap)]Cl Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-xylbinap)]Cl
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CAS | 944451-25-6
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944451-25-6 - Physico-chemical Properties
Molecular Formula | C62H62Cl2P2R
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Molar Mass | 1041.1 |
Melting Point | >100°C |
Appearance | Powder |
Color | orange to brown |
Storage Condition | Room Temprature |
Sensitive | air sensitive |
944451-25-6 - Introduction
Choro {(S)-(-)-2,2 '-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-xylbinap)]Cl (often abbreviated as [RuCl(p-cymene)((S)-xylbinap)]Cl) it is a ruthenium-containing organometallic compound with the following properties, uses, methods and safety information:
Nature:
-Appearance: Colorless crystalline solid
-Molecular formula: C56H53Cl3P2Ru
-Molecular weight: 971.66g/mol
-Melting point: 163-168 ° C
-Insoluble in water, soluble in organic solvents such as ethanol and chloroform
Use:
- [RuCl(p-cymene)((S)-xylbinap)]Cl is a chiral ligand complex, which is widely used in asymmetric catalytic reactions to promote the preparation of chiral organic compounds.
-commonly used in asymmetric hydrogenation, asymmetric hydrogen addition, Asymmetric oxidation and other reactions.
Method:
-Usually synthesized by coordination reaction: First react [RuCl(p-cymene)Cl2]2 with (S)-xylbinap to generate [RuCl(p-cymene)((S)-xylbinap)]Cl.
Safety Information:
- [RuCl(p-cymene)((S)-xylbinap)]Cl may be harmful to the environment and requires proper disposal of waste and residues.
-In case of skin contact or inhalation, seek medical attention.
-storage should avoid direct light, to be placed in a dry, ventilated place.
Last Update:2024-04-10 22:29:15