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463941-07-3

(3aS)-1-(2-methylphenyl)-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole

CAS: 463941-07-3

Molecular Formula: C24H24BNO

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463941-07-3 - Names and Identifiers

Name (3aS)-1-(2-methylphenyl)-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole
Synonyms (S)-(-)-o-Tolyl-CBS-oxazaborolidine
(S)-o-tol-Corey-Bakshi-Shibata catalyst
(s)-(-)-o-tolyl-cbs-oxazaborolidine solution
(S)-(-)-o-Tolyl-CBS-oxazaborolidine solution 0.5 M in toluene
(s)-(-)-3,3-diphenyl-1-o-tolyl-tetrahydropyrrolo(1,2-c)(1,3,2)oxazaborole solution
(3aS)-1-(2-methylphenyl)-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole
1H,3H-Pyrrolo[1,2-c][1,3,2]oxazaborole, tetrahydro-1-(2-methylphenyl)-3,3-diphenyl-, (3aS)-
(S)-()-o-Tolyl-CBS-oxazaborolidine solution,(S)-()-3,3-Diphenyl-1-o-tolyl-tetrahydropyrrolo(1,2-c)(1,3,2)oxazaborole solution
CAS 463941-07-3
InChI InChI=1/C24H24BNO/c1-19-11-8-9-16-22(19)25-26-18-10-17-23(26)24(27-25,20-12-4-2-5-13-20)21-14-6-3-7-15-21/h2-9,11-16,23H,10,17-18H2,1H3/t23-/m0/s1

463941-07-3 - Physico-chemical Properties

Molecular FormulaC24H24BNO
Molar Mass353.26
Density0.9009g/mLat 25°C
Boling Point473.3±55.0 °C(Predicted)
Flash Point7°C
Vapor Presure3.96E-09mmHg at 25°C
pKa-0.32±0.40(Predicted)
Refractive Indexn20/D 1.514

463941-07-3 - Risk and Safety

Risk CodesR11 - Highly Flammable
R38 - Irritating to the skin
R48/20 -
R63 - Possible risk of harm to the unborn child
R65 - Harmful: May cause lung damage if swallowed
R67 - Vapors may cause drowsiness and dizziness
Safety DescriptionS36/37 - Wear suitable protective clothing and gloves.
S62 - If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
S16 - Keep away from sources of ignition.
UN IDsUN 1294 3/PG 2
WGK Germany3

463941-07-3 - Reference Information

Use When chiral zoborane is protonated with trifluoromethanesulfonimide, chiral Lewis acid can be generated. It has been confirmed that this acid is very suitable for enantioselective Diels-Alder reactions. 1,2
Last Update:2024-04-09 21:04:16
463941-07-3
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