2-降莰烷甲醇,内型和外型混合物
2-norbornanemethanol, mixture of endo and ex
CAS: 5240-72-2
Molecular Formula: C8H14O
2-降莰烷甲醇,内型和外型混合物 - Names and Identifiers
2-降莰烷甲醇,内型和外型混合物 - Physico-chemical Properties
| Molecular Formula | C8H14O |
| Molar Mass | 126.2 |
| Density | 0.942g/mLat 25°C(lit.) |
| Boling Point | 93-95°C14mm Hg(lit.) |
| Flash Point | 184°F |
| Water Solubility | 999mg/L(temperature not stated) |
| Vapor Presure | 0.124mmHg at 25°C |
| Appearance | clear liquid |
| Color | Colorless to Yellow to Orange |
| pKa | 15.05±0.10(Predicted) |
| Storage Condition | Room Temprature |
| Refractive Index | n20/D 1.49(lit.) |
| MDL | MFCD00074722 |
2-降莰烷甲醇,内型和外型混合物 - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
| UN IDs | UN 2810 6.1/PG 3 |
| WGK Germany | 3 |
| RTECS | RB7350000 |
| Hazard Class | 6.1(b) |
| Packing Group | III |
| Toxicity | LD50 orl-rat: 1600 mg/kg 28ZEAL 4,302,69 |
2-降莰烷甲醇,内型和外型混合物 - Reference Information
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| use | 2-norcamphane methanol can be used as an intermediate in pharmaceutical synthesis. |
| Preparation | Add Ru precursor (1.6mol%) and imidazolium to norbornene methanol. The CO2/H2 pressurized reactor was warmed to the desired reaction temperature for 17 h. The reactor was cooled and the product was extracted with Et2O(3 × 15mL) to obtain 2-norcamphane methanol. |
Last Update：2024-04-09 21:11:58
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View History
2-降莰烷甲醇,内型和外型混合物
3-(3-FLUOROPHENYL)PROPRIONIC ACID
2-异丁氧基-4-(三氟甲基)苯基硼酸
三(二萘基亚甲基) 单菲咯啉铕/(III)
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氯化双(5-茂二甲基铝-甲基钛)
四甲基三乙酰氧基硼氢化铵
[4-(甲基硫基)苯氧基]乙酸
4-(4-氯苯基)-2-[(2-氰基乙酰基)氨基]噻吩-3-羧酸乙酯
3-(3-FLUOROPHENYL)PROPRIONIC ACID
2-异丁氧基-4-(三氟甲基)苯基硼酸
三(二萘基亚甲基) 单菲咯啉铕/(III)
GAMMA-GLUTAMYL-SE-METHYLSELENOCYSTEINE
TERT-BUTYL 8-HYDROXY-5-AZASPIRO[3.5]NONANE-5-CARBOXYLATE
氯化双(5-茂二甲基铝-甲基钛)
四甲基三乙酰氧基硼氢化铵
[4-(甲基硫基)苯氧基]乙酸
4-(4-氯苯基)-2-[(2-氰基乙酰基)氨基]噻吩-3-羧酸乙酯