Name | (+)-B-chlorodiisopinocampheylborane |
Synonyms | oroborane (+)-DIPChloride (+)-DIP chloride (+)-DiisopinocampheyL (+)-Diisopinocampheyl chloroborane (+)-B-chlorodiisopinocampheylborane (+)-β-Chlorodiisopinocampheylborane (+)-DiisopinocaMpheylchloroborane in heptanes (+)-B-Chlorodiisopinocampheylborane((+)-DIP-Chloride) (+)-DIP-Chloride,(+)-B-Chlorodiisopinocampheylborane, (+)-Ipc2BCl (+)-Diisopinocampheylchloroborane, 1.8M solution in hexanes, AcroSeal Chlorobis((1S,2R,3S,5S)-2,6,6-triMethylbicyclo[3.1.1]heptan-3-yl)borane chloro{bis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]}borane chloro[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl][(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]borane |
CAS | 112246-73-8 |
InChI | InChI=1/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12+,13+,14-,15-,16+,17-,18+ |
InChIKey | PSEHHVRCDVOTID-YYNWCRCSSA-N |
Molecular Formula | C20H34BCl |
Molar Mass | 320.75 |
Density | 0.91 |
Melting Point | 53-55°C(lit.) |
Boling Point | 369.6±25.0 °C(Predicted) |
Flash Point | >230°F |
Vapor Presure | 2.5E-05mmHg at 25°C |
Appearance | clear liquid |
Color | Colorless to Almost colorless |
Storage Condition | 2-8°C |
Refractive Index | 1.5 |
MDL | MFCD00074808 |
Physical and Chemical Properties | Melting point 53-55°C flash point> 110°C |
Hazard Symbols | C - Corrosive![]() |
Risk Codes | R34 - Causes burns R37 - Irritating to the respiratory system |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
UN IDs | UN 3261 8/PG 2 |
WGK Germany | 3 |
FLUKA BRAND F CODES | 10-21 |
HS Code | 29319090 |
Hazard Class | 8 |
Packing Group | III |
introduction | ( )-diisopinylchloroborane is a highly active borane compound. Highly active borane compounds refer to those borane compounds with strong reducing ability, including borane complexes, such as alkane tetrahydrofuran complexes, borane dimethyl sulfide complexes, borane tert-butylamine complexes, Borane N,N-diethylaniline complex, borane trimethylamine complex, borane pyridine complex, borane amine complex, borane triethylamine complex, etc. |
Use | ( )-diisopinylchloroborane can be used as an excellent reagent for asymmetric reduction reactions,( )-and (-)-DIP-chloride can be used for asymmetric reduction of prochiral ketones The preparation of β-amino alcohols. pharmaceutical intermediates |
application | ( )-diisopinylchloroborane is an organic synthesis intermediate and a pharmaceutical intermediate, which can be used in laboratory research and development processes and chemical and biomedical synthesis processes. |