1,1′-双(二-叔丁基膦基)二茂铁二氯合钯(II)
1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride
CAS: 95408-45-0
Molecular Formula: C26H38Cl2FeP2Pd
1,1′-双(二-叔丁基膦基)二茂铁二氯合钯(II) - Names and Identifiers
| Name | 1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride |
| Synonyms | PdCl2(dtbpf) 1,1'-Bis (di-t-butylphosphino) [1,1'-Bis(di-tert-butylphosphino)ferrocene]dichlor 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II) 1,1′-Bis-(di-tert.-butylphosphino-)ferrocen-palladiumdichlorid 1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride Dichloro[1,1'-bis(di-i-propylphosphino)ferrocene]palladium (II) [1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) Dichloro [1,1' bis(di-tert-butylphosphino)]ferrocene palladium (II) |
| CAS | 95408-45-0 |
| EINECS | 664-483-5 |
| InChI | InChI=1/2C13H22P.2ClH.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h2*7-10H,1-6H3;2*1H;;/q;;;;;+2/p-2/rC26H44FeP2.2ClH.Pd/c1-23(2,3)28(24(4,5)6)21-17-13-15-19(21)27-20-16-14-18-22(20)29(25(7,8)9)26(10,11)12;;;/h13-20H,1-12H3;2*1H;/q;;;+2/p-2 |
1,1′-双(二-叔丁基膦基)二茂铁二氯合钯(II) - Physico-chemical Properties
| Molecular Formula | C26H38Cl2FeP2Pd |
| Molar Mass | 645.7 |
| Melting Point | 203-208°C |
| Solubility | Soluble in dichloromethane and chloroform. Partially soluble in acetone, alcohols, tertrahydrofuran and dioxane. |
| Appearance | crystal |
| Color | dark purple |
| Storage Condition | -20°C |
| MDL | MFCD08064219 |
| Use | High-efficiency catalysts for cross-coupling reactions |
1,1′-双(二-叔丁基膦基)二茂铁二氯合钯(II) - Risk and Safety
| Safety Description | 24/25 - Avoid contact with skin and eyes. |
| WGK Germany | 3 |
| HS Code | 28439000 |
1,1′-双(二-叔丁基膦基)二茂铁二氯合钯(II) - Reference Information
| Introduction | [1,1 '-bis (diphenylphosphino) ferrocene] palladium (II) dichloride it is a palladium complex of an iron-containing ligand, dppf. This is a commercially available reagent commonly used in palladium-catalyzed coupling reactions. |
| preparation | dichloro [1,1 '-bis (tert-butylphosphine) ferrocene palladium (II) dppf PdCl2(RCN)2 → (dppf)PdCl2 2 RCN (RCN = acetonitrile or benzonitrile) can be prepared by reaction of dppf with cyano-complexed palladium chloride. |
| Use | dichloro [1,1 '-bis (tert-butylphosphine) ferrocene palladium (II) can be used as catalyst, suzuki cross-coupling reactions for various aromatic and isoaromatic halides with methanesulfonyl diacetic acid derivatives. |
Last Update：2024-04-10 22:29:15
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