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六甲基二硅烷

Hexamethyldisilane

CAS: 1450-14-2

Molecular Formula: C6H18Si2

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六甲基二硅烷 - Names and Identifiers

Name Hexamethyldisilane
Synonyms HMD
CH7280
(CH3)6Si2
DISILANE M6
Hexamethyldisilane
HEXAMETHYLDISILANE
Hecamethyldisilane
disilane,hexamethyl-
Hexamethyl disilylamine
1,1,1,2,2,2-Hexamethyldisilane
CAS 1450-14-2
EINECS 215-911-0
InChI InChI=1/C6H18Si2/c1-7(2,3)8(4,5)6/h1-6H3
InChIKey NEXSMEBSBIABKL-UHFFFAOYSA-N

六甲基二硅烷 - Physico-chemical Properties

Molecular FormulaC6H18Si2
Molar Mass146.38
Density0.715 g/mL at 25 °C (lit.)
Melting Point9-12 °C (lit.)
Boling Point112-114 °C (lit.)
Flash Point29°F
Water SolubilityInsoluble in water. Soluble in alcohol, ether and acetone.
Solubility sol common organic solvents; insol H2O.
Vapor Presure24.5mmHg at 25°C
Appearanceliquid
Specific Gravity0.729
Colorcolorless
BRN1633463
Storage ConditionStore at
StabilityVolatile
Sensitive1: no significant reaction with aqueous systems
Refractive Indexn20/D 1.422(lit.)
Physical and Chemical Properties

Properties: colorless transparent liquid, pleasant fruit odor
solubility insoluble in water, soluble in xylene, benzene, ethylene glycol dimethyl ether and other solvents

UseUsed as a raw material for the synthesis of trimethylsilyl lithium, trimethylsilyl sodium, trimethylsilyl potassium; Used in pharmaceutical synthesis, can be used as a termination agent of polysiloxane chain

六甲基二硅烷 - Risk and Safety

Risk CodesR11 - Highly Flammable
R36/37 - Irritating to eyes and respiratory system.
R43 - May cause sensitization by skin contact
R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS16 - Keep away from sources of ignition.
S23 - Do not breathe vapour.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S9 - Keep container in a well-ventilated place.
S33 - Take precautionary measures against static discharges.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S7/9 -
UN IDsUN 1993 3/PG 2
WGK Germany2
RTECSJM9170000
TSCAYes
HS Code29310095
Hazard Class3
Packing GroupII
ToxicityLD50 orally in Rabbit: 2160 mg/kg LD50 dermal Rabbit 2160 mg/kg

六甲基二硅烷 - Reference Information

NIST chemical information information provided by: webbook.nist.gov (external link)
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
Use hexamethyldisilane sodium trimethylsilane, potassium trimethylsilane and lithium trimethylsilane can be synthesized. Iodotrimethylsilane was prepared. As an important protective agent of trimethylsilane anion reagent
, it can be used in the synthesis of antibiotics such as ceftazidime.
used as a source material for vapor deposition during silicon carbide growth; A silylating agent for Allyl acetate, aryl halides, and diketones.
used as raw materials for the synthesis of trimethylsilyl lithium, trimethylsilyl sodium, trimethylsilyl potassium
used in pharmaceutical synthesis, can be used as a termination agent of polysiloxane chain.
Last Update:2024-04-09 02:00:04
六甲基二硅烷
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View History
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