zincethylhexanoate
Zinc ethylhexanoate
CAS: 136-53-8
Molecular Formula: C16H30O4Zn
zincethylhexanoate - Names and Identifiers
| Name | Zinc ethylhexanoate |
| Synonyms | zincethylhexanoate zinc2-ethylcaproate Zinc ethylhexanoate Zinc 2-Ethylcaproate Zinc 2-ethylhexanoate Zinc (II)-2 ethyhexanote zinc(II) 2-ethylhexanoate zinc bis(2-ethylhexanoate) 2-ethyl-hexanoicacizincsalt Ethylhexanoic acid zinc salt Ethylhexanoic Acid Zinc Salt Hexanoicacid,2-ethyl-,zincsalt Zincethylhexanoatecainmineralspiritsoffwhiteviscous |
| CAS | 136-53-8 |
| EINECS | 205-251-1 |
| InChI | InChI=1/2C8H16O2.Zn/c2*1-3-5-6-7(4-2)8(9)10;/h2*7H,3-6H2,1-2H3,(H,9,10);/q;;+2/p-2 |
zincethylhexanoate - Physico-chemical Properties
| Molecular Formula | C16H30O4Zn |
| Molar Mass | 351.8 |
| Density | 1,17 g/cm3 |
| Melting Point | 115-117℃ |
| Boling Point | 228°C at 760 mmHg |
| Flash Point | 40°C |
| Water Solubility | Not miscible or difficult to mix in water. |
| Vapor Presure | 0.027mmHg at 25°C |
| Appearance | Liquid |
| Specific Gravity | 1.07 |
| Exposure Limit | ACGIH: TWA 100 ppmOSHA: TWA 500 ppm(2900 mg/m3)NIOSH: IDLH 20000 mg/m3; TWA 350 mg/m3; Ceiling 1800 mg/m3 |
| Storage Condition | Room Temprature |
| Sensitive | 4: no reaction with water under neutral conditions |
| MDL | MFCD00053316 |
| Physical and Chemical Properties | Zinc 2-ethylhexanoate, also known as zinc isooctanoate, zinc octoate, light yellow uniform transparent liquid. Density 1.17g/cm3. This product has excellent Storage Stability. Compared with traditional zinc naphthenate, zinc isooctanate has the characteristics of light color, small odor and high content. |
| Use | Mainly used as coating drier, in the use of white paint has better characteristics |
zincethylhexanoate - Risk and Safety
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| UN IDs | 1993 |
| TSCA | Yes |
| Hazard Class | 3 |
| Packing Group | III |
zincethylhexanoate - Reference Information
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| uses and functions | this product is used as a catalyst for polyurethane coatings and elastomers, which can promote crosslinking of aliphatic isocyanates, shorten curing time, and is also used as a heat stabilizer for PVC plastics. this product is also an excellent wetting agent for coatings, which can be used as suspending agent, matting agent, dispersant and boat primer antifouling agent, etc. As a gelling agent in ink; Can be used as oil additive; Anti-corrosion, anti-mold agent, etc. |
| Preparation of zinc isooctanoate by precipitation method | The precipitation method uses sodium hydroxide, isooctanoate and zinc sulfate as raw materials to prepare zinc isooctanoate through saponification reaction and metathesis reaction. The first step of the precipitation method is to make sodium soap first, that is, sodium hydroxide reacts with isooctanoic acid to form sodium soap (sodium isooctanoate). The chemical equation of the reaction is as follows: RCOOH NaOH = RCOONAH2O formula: R is CH3(CH2)3CH(C2H5) After the saponification reaction is completed, zinc sulfate solution is used for replacement to generate zinc isooctanate. The chemical equation of the reaction is as follows: 2RCOONa ZnSO4 = Zn (RCOO)2 Na2SO4 formula: r is CH3(CH2)3CH (C2H5) synthesis step: add a certain amount of isooctanoic acid and sodium hydroxide solution into the reactor, stir and raise the temperature to a certain temperature for saponification reaction, then add a certain amount of mineral oil and zinc sulfate solution, and react under full stirring. After the reaction is complete, let it stand and stratify, separate the lower water phase, and then clean the upper oil layer with hot water for 2~3 times, and analyze the zinc content in the washing solution. Then the upper oil phase is dehydrated by vacuum distillation to obtain the zinc isooctanate product, and the zinc content is determined, and the yield of the corresponding zinc isooctanate is calculated. |
| toxicity and hygiene | zinc 2-ethylhexanoate has a stimulating effect on skin and mucous membranes. GB 9685-2008 stipulates that (1) the maximum amount of zinc isooctanoate is 1.0% in plastic PE and PP; PS is 0.1%; Adhesives and paper shall be used appropriately according to production requirements;(2) The specific migration amount (SML, calculated as zinc) is 25.0 mg/kg. |
| use | is mainly used as a paint drier, and it has better characteristics when used in white paint |
Last Update：2024-04-10 22:29:15
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