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dichlororuthenium

(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride

CAS: 145926-28-9

Molecular Formula: C54H46Cl2P2Ru

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dichlororuthenium - Names and Identifiers

Name (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride
Synonyms dichlororuthenium
1-isopropyl-4-methyl-benzene
(R)-RuCl[(p-cymene)(BINAP)]Cl
S-(-)-BINAP-Chloro(P-cymene)ruthenium chloride
[1-(2-diphenylphosphanyl-1-naphthyl)-2-naphthyl]-diphenyl-phosphane
(R)-(+)-2,2'-[Bis(diphenylphosphino)-1,1'-Binaphthyl]Chloro(P-cymene)ruthenium
(R)-(+)-2,2'-[BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RU CHLORIDE
[(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE
[(S)-2,2'-Bis-(diphenylphosphino)-1,1'-Binaphthyl]-Chloro-(P-cymene)-rutheniumchloride
[(R)-2,2'-Bis-(diphenylphosphino)-1,1'-Binaphthyl]-Chloro-(P-cymene)-rutheniumchloride
[(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE
(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
(R)-(+)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthalenechloro(P-Cymene)Ruthenium Chloride
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride
Chloro[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride
Chloro[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-Binaphthyl](P-cymene)ruthenium (II) chloride
Chloro[(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-Binaphthyl](P-cymene)ruthenium (II) chloride
Chloro[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride, [RuCl(p-cymene)((R)-binap)]Cl
CAS 145926-28-9
EINECS 664-469-9
InChI InChI=1/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

dichlororuthenium - Physico-chemical Properties

Molecular FormulaC54H46Cl2P2Ru
Molar Mass928.87
Melting Point>100°C
Boling Point724.3°C at 760 mmHg
Flash Point419°C
Vapor Presure5.55E-20mmHg at 25°C
AppearancePowder
Colororange
Storage Condition2-8°C
SensitiveAir Sensitive
Physical and Chemical PropertiesStorage Conditions: Freezer (-20 °c)

dichlororuthenium - Risk and Safety

Hazard SymbolsXn - Harmful
Harmful
Risk CodesR68/20/21/22 -
R36/37/38 - Irritating to eyes, respiratory system and skin.
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
Safety DescriptionS45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany3
HS Code28439000

dichlororuthenium - Introduction

(R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride is an organometallic compound with the chemical formula C44H32Cl2P2Ru. It is a dark red crystal, soluble in some organic solvents.

(R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride is usually used as a catalyst, it has a wide range of applications in organic synthesis reactions. It can catalyze olefin hydrogenation reaction, carbonylation reaction and olefin cyclization reaction. In addition, it can also be used for asymmetric catalytic reactions and asymmetric synthesis.

Preparation of (R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene) A common method of ruthenium chloride is to react [RuCl2(p-cymene)]2 with (DPPF), where p-cymene is a cycloheptanenated cyclic hydrocarbon and DPPF is Bis (diphenylphosphine) biphenyl.

For safety information,(R)-( )-2,2 '-Bis(diphenylphosphino)-1,1'-binaphthaleneChloro(P-cymene)ruthenium chloride is relatively stable under general conditions of use. However, in handling and use, it is still necessary to comply with laboratory safety practices and specifications, and avoid direct contact with eyes, skin and respiratory tract. At the same time, it should be operated in a well-ventilated place to avoid inhaling its vapor. If exposed to skin or inhaled, rinse immediately with water and seek medical advice.
Last Update：2024-04-10 22:29:15
dichlororuthenium
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View History
dichlororuthenium
5952-92-1
401-78-5
140-90-9
117-34-0
Hepta sodium salt of Diethylene Triamine Penta (Methylene Phosphonic Acid)
3350-13-8
41448-29-7
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