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TRIS(DIMETHYLAMINO)SILANE

Tris(dimethylamino)silane

CAS: 15112-89-7

Molecular Formula: C6H19N3Si

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TRIS(DIMETHYLAMINO)SILANE - Names and Identifiers

Name Tris(dimethylamino)silane
Synonyms BRN 1901643
tris(dimethylamino)silyl
Tris(dimethylamino)silane
TRIS(DIMETHYLAMINO)SILANE
N,N',N''-Silanetriyltris(dimethylamine)
N,N',N''-(Silanetriyl)tris(dimethylamine)
n,n,n',n',n'',n''-hexamethylsilanetriamine
n,n,n',n',n'',n''-hexamethyl-silanetriamin
N,N,N',N',N'',N''-Hexamethylsilanetriamine
N,N,N',N',N'',N''-hexamethyl-Silanetriamine
Silanetriamine, N,N,N',N',N'',N''-hexamethyl-
CAS 15112-89-7
EINECS 239-165-0
InChI InChI=1/C6H18N3Si/c1-7(2)10(8(3)4)9(5)6/h1-6H3

TRIS(DIMETHYLAMINO)SILANE - Physico-chemical Properties

Molecular FormulaC6H19N3Si
Molar Mass161.32
Density0,838 g/cm3
Boling Point145 °C
Flash Point25°C
Appearanceliquid
Specific Gravity0.84
Colorcolorless to light yellow
pKa10.93±0.70(Predicted)
Storage ConditionRoom Temprature
Sensitive8: reacts rapidly with moisture, water, protic solvents
Refractive Index1.4247

TRIS(DIMETHYLAMINO)SILANE - Risk and Safety

Risk CodesR10 - Flammable
R36/37/38 - Irritating to eyes, respiratory system and skin.
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R34 - Causes burns
R29 - Contact with water liberates toxic gas
R20 - Harmful by inhalation
R15 - Contact with water liberates extremely flammable gases
R11 - Highly Flammable
Safety DescriptionS16 - Keep away from sources of ignition.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
UN IDs1993
WGK Germany3
RTECSVV5800000
TSCAYes

TRIS(DIMETHYLAMINO)SILANE - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
product characteristics related studies show that tris (dimethylamino) silane as a precursor source not only has better stability and higher vapor pressure, but also shows quite high reactivity, so this silicone source has become a hot spot in the research of ALD method deposition of SiO2.
Preparation A method for preparing tris (dimethylamine) silane, which includes the following steps: under the protection of an inert atmosphere, adding dimethylamine and hydrocarbon in the reactor Solvent, and then adding an organolithium compound to the system to obtain a lithium salt of dimethylamine; adding trichlorosilane to the system; distilled after the reaction, tris (dimethylaminoyl) silane is obtained.
Last Update:2024-04-09 02:00:07
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TRIS(DIMETHYLAMINO)SILANE
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