Rhodium

Rhodium - Names and Identifiers

Name	Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Synonyms	rhodium trifluoromethanesulfonate (1Z,5Z)-cycloocta-1,5-diene Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate BIS(1,5-CYCLOOCTADIENE)-TRIFLUOROMETHANESULFITORHODIUM (I) BIS(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS	99326-34-8
InChI	InChI=1/2C8H12.CHF3O3S.Rh/c21-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h21-2,7-8H,3-6H2;(H,5,6,7);/p-1/b2*2-1-,8-7-;

Rhodium - Physico-chemical Properties

Molecular Formula	C17H24F3O3RhS
Molar Mass	468.34
Melting Point	159°C (dec.)(lit.)
Boling Point	153.5°C at 760 mmHg
Flash Point	31.7°C
Water Solubility	insoluble
Solubility	Soluble in chloroform
Vapor Presure	4.25mmHg at 25°C
Appearance	Solid
Color	dark red
Exposure Limit	ACGIH: TWA 1 mg/m3NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
Storage Condition	Inert atmosphere,Room Temperature
Sensitive	Air Sensitive
MDL	MFCD00143752

Rhodium - Risk and Safety

Hazard Symbols	Xi - Irritant
Risk Codes	36/37/38 - Irritating to eyes, respiratory system and skin.
Safety Description	26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany	3
TSCA	No
HS Code	28439000
Hazard Note	Irritant

Rhodium - Introduction

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate is a platinum group metal complex with the chemical formula [C8H12]2Rh(CF3SO3). Here is some information about the compound:

Nature:
- Bis(1,5-cyclo octadiene)rhodium(I) trifluoromethanesulfonate is a red-brown solid in an organic solvent.
-It is soluble in organic solvents, but almost insoluble in water.
-It is sensitive to air and water, and should be stored and operated under an inert atmosphere.

Use:
- Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate are commonly used as catalysts, especially in organic synthesis.
-It has a wide range of applications in the synthesis of organic compounds, polymers and hybrid materials.
-As a catalyst, it can catalyze various chemical reactions, such as hydrogenation of olefins, asymmetric synthesis, etc.

Preparation Method:
- Bis(1,5-cyclo octadiene)rhodium(I) trifluoromethanesulfonate are generally prepared by synthetic methods.
-A common preparation method includes reacting rhodium fluoromethanesulfonate with 1,5-cyclooctadiene and ammonium rhodium oxide to generate Bis (1,5-cycloctadiene) rhodium(I) trifluoromethanesulfonate.

Safety Information:
- Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate need to be careful when using and operating because it is sensitive to air and water.
-Appropriate safety measures should be taken during operation, such as wearing appropriate personal protective equipment and operating in a well-ventilated area.
-Due to its toxicity and reactivity, the compound should be stored in a sealed container and away from flammable materials and strong oxidants.
-When using this compound, please refer to more detailed safety and operation guidelines, and follow the standard operating procedures of the laboratory.

Last Update：2024-04-10 22:29:15

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