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Propetamphos

Propetamphos

CAS: 31218-83-4

Molecular Formula: C10H20NO4PS

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Propetamphos - Names and Identifiers

Name Propetamphos
Synonyms Blotic
Safrotin
Propetamphos
1-methylethyl (2E)-3-{[(ethylamino)(methoxy)phosphorothioyl]oxy}but-2-enoate
1-methylethyl (2Z)-3-{[(ethylamino)(methoxy)phosphorothioyl]oxy}but-2-enoate
CAS 31218-83-4
EINECS 250-517-2
InChI InChI=1/C10H20NO4PS/c1-6-11-16(17,13-5)15-9(4)7-10(12)14-8(2)3/h7-8H,6H2,1-5H3,(H,11,17)/b9-7-

Propetamphos - Physico-chemical Properties

Molecular FormulaC10H20NO4PS
Molar Mass281.31
Density1.15g/cm3
Melting Point<25℃
Boling Point321.1°C at 760 mmHg
Flash Point148°C
Water Solubility110 mg l-1(24°C)
Vapor Presure0.000304mmHg at 25°C
Appearancemorphology neat
pKa0.94±0.70(Predicted)
Storage Condition2-8°C
Refractive Index1.494
Physical and Chemical PropertiesChemical properties light yellow oily liquid. Boiling point 87-89 ℃(6.65 × 10-4kPa), relative density 1.1294(20/4 ℃), refractive index 1.495. The solubility in 24 ℃ water is 110mg/L, which is soluble in most organic solvents. Stable to heat and light.
UseHas the effect of killing and stomach poison, mainly used to control cockroaches, flies and mosquitoes and other pests

Propetamphos - Risk and Safety

Risk CodesR25 - Toxic if swallowed
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
Safety DescriptionS37 - Wear suitable gloves.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60 - This material and its container must be disposed of as hazardous waste.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
UN IDs3018
WGK Germany3
RTECSGQ4750000
HS Code29299090
Hazard Class6.1(b)
Packing GroupII
ToxicityLD50 orally in male rats: 82 mg/kg (Berg, Gothe)

Propetamphos - Upstream Downstream Industry

Raw Materialso-Xylene
Methyl alcohol
thiophosphoryl chloride

Propetamphos - Nature

Merck 13,7907
BRN 1979853
EPA chemical information Propetamphos (31218-83-4)
Last Update:2024-04-10 22:29:15

Propetamphos - Uses and synthesis methods

use

1. alkylene phosphorus is a contact insecticide, which is used for stomach toxicity. It can effectively control cockroaches, flies, mosquitoes and other pests, as well as cow lice.

2. It has contact and stomach poison effects, mainly used to control pests such as cockroaches, flies and mosquitoes

production method

In the presence of catalyst and acid binding agent, the intermediate obtained by the reaction of 3-hydroxybutenoic acid isopropyl ester and thiophosphoryl chloride is condensed with methanol and ethylamine to obtain alkylene phosphorus. In industrial production, tributylamine is added to the mixture of isopropyl acetoacetate and thiophosphoryl chloride, stirred and cooled at -3 ℃ during feeding, continued to stir at 0-3 ℃ for 4.5h, separated viscous oily liquid, added toluene and petroleum ether, filtered out tributylammonium chloride, the filtrate is concentrated in vacuum at a bath temperature of 30 ℃, methanol is added to the residue, reduced to 0 ℃ as quickly as possible, the feeding temperature is -5 ℃, mixed at 0 ℃ and stirred for 4.5h. The reaction mixture is extracted twice with about 10% hydrochloric acid solution. Adding petroleum ether during the second extraction is conducive to extraction. The petroleum ether is washed with water and alkali, and dried with anhydrous sodium sulfate to remove the solvent to obtain alkylene phosphorus. Raw material consumption quota: tributylamine 670kg/t, isopropyl acetoacetate 520kg/t, phosphoryl chloride 650kg/t, methanol 470kg/t, ethylamine (70%)820kg/t.

Last Update:2024-04-10 22:29:15

Propetamphos - Security information

toxic substance data 31218-83-4(Hazardous Substances Data)
Last Update:2024-04-09 01:59:50
Propetamphos
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Shanghai Yuanye Bio-Technology Co., Ltd.
Multiple Specifications
Product Name: Propetamphos Visit Supplier Webpage Request for quotation
CAS: 31218-83-4
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
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View History
Propetamphos
HEXENAL
Raw Materials for Propetamphos
o-Xylene
Methyl alcohol
thiophosphoryl chloride
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