Periodate
Periodic acid
CAS: 10450-60-9
Molecular Formula: H5IO6
Periodate - Names and Identifiers
| Name | Periodic acid |
| Synonyms | Periodate Periodic acid Periodic Acid, ACS Periodic(Vii) Acid PERIODIC ACID FOR ANALYSIS EMSURE pentahydroxy-lambda~5~-iodane oxide Periodic acid SynonyMs Orthoperiodic acid |
| CAS | 10450-60-9 |
| EINECS | 233-937-0 |
| InChI | InChI:1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7) |
| InChIKey | TWLXDPFBEPBAQB-UHFFFAOYSA-N |
Periodate - Physico-chemical Properties
| Molecular Formula | H5IO6 |
| Molar Mass | 227.94057 |
| Density | d417 1.3875; d 1.42 |
| Melting Point | 122 °C (lit.) |
| Boling Point | 140°C |
| Flash Point | 140°C |
| Water Solubility | Soluble in water and alcohols. |
| Vapor Presure | 7.6Pa at 25℃ |
| Appearance | Solid |
| Color | White to slightly yellow |
| Merck | 14,7171 |
| PH | 1.2 (100g/l, H2O, 20℃) |
| Storage Condition | Store at +15°C to +25°C. |
| Stability | Stable, but strong oxidizer. Contact with combustible material may cause fire. Hygroscopic. Incompatible with organic materials, strong reducing agents. |
| Sensitive | Moisture & Light Sensitive |
| Physical and Chemical Properties | Colorless or white crystals, odorless, deliquescent; Boiling point 140 ℃ (decomposition); Melting point 122 ℃; Solubility: soluble in water, ethanol, slightly soluble in ether; Density: relative density (Air = 1)7.9; Stability: stable; Hazard marker 11 (oxidant); Main use: used as oxidant |
| Use | Used as a reagent for chromatographic analysis |
Periodate - Risk and Safety
| Risk Codes | R8 - Contact with combustible material may cause fire R34 - Causes burns |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S27 - Take off immediately all contaminated clothing. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S17 - Keep away from combustible material. S36 - Wear suitable protective clothing. |
| UN IDs | UN 3264 8/PG 2 |
| WGK Germany | 3 |
| RTECS | NN1269700 |
| FLUKA BRAND F CODES | 3-8 |
| TSCA | Yes |
| HS Code | 2811 19 80 |
| Hazard Class | 5.1 |
| Packing Group | II |
Periodate - Upstream Downstream Industry
Periodate - Reference Information
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Use | used as a reagent for chromatographic analysis used as an oxidant oxidant. Electrophoretic grade for glycoprotein staining |
| production method | method 1. After passing through a column filled with a KY-2(H-type) exchanger, heating, evaporation and concentration are carried out until crystallization begins, and then the sulfuric acid dryer is discharged, the precipitated crystals were removed and then dried in a desiccator. Methods 2. Soak barium periodate with a small amount of water, add an excess of concentrated nitric acid with a relative density of 1.42 (find out, do not contain nitrogen oxides), heat to 60~70 oC, cool, stand, and stir constantly, let it fully react: After the reaction is finished, cool to 30~40 ℃, filter out barium nitrate precipitate, wash the precipitate with concentrated nitric acid to not contain periodic acid, wash and filtrate, together with reduced pressure evaporation concentration (60~70 deg C), after cooling and standing, so that colorless periodic acid completely crystallized, the filtered crystals were dried under reduced pressure at 50 oC, periodic acid with a purity of 99.5% to 99.9% was obtained. |
Last Update：2024-04-10 22:29:15
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Raw Materials for Periodate