Fortrol
Fortrol
CAS: 21725-46-2
Molecular Formula: C9H13ClN6
Fortrol - Names and Identifiers
| Name | Fortrol |
| Synonyms | Bladex Gramex CY-PRO BLADEX Fortrol CYANAZIN CYANAZINE Cyanazine Cyanizine 'LGC' (1635) 2-Chloro-4-((1-cyano-1-methylethyl)amino)-6-(ethylamino)-s-triazine 2-(4-CHLORO-6-ETHYLAMINO-S-TRIAZIN-2-YL AMINO)-2-METHYLPROPIONITRILE 2-(4-CHLORO-6-(ETHYLAMINO)-1,3,5-TRIAZIN-2-YLAMINO)-2-METHYLPROPANENITRILE 2-{[4-chloro-6-(ethylamino)-1,3,5-triazin-2-yl]amino}-2-methylpropanenitrile 2-[[4-Chloro-6-(ethylamino)-1,3,5-triazin-2-yl]amino]-2-methylpropanenitrile |
| CAS | 21725-46-2 |
| EINECS | 244-544-9 |
| InChI | InChI=1/C9H13ClN6/c1-4-12-7-13-6(10)14-8(15-7)16-9(2,3)5-11/h4H2,1-3H3,(H2,12,13,14,15,16) |
Fortrol - Physico-chemical Properties
| Molecular Formula | C9H13ClN6 |
| Molar Mass | 240.69 |
| Density | 1.2870 (rough estimate) |
| Melting Point | 167°C |
| Boling Point | 383.12°C (rough estimate) |
| Flash Point | 100°C |
| Water Solubility | 0.0171 g/100 mL |
| Solubility | Slightly soluble in water, soluble in ethanol, benzene, chloroform, hexane. |
| Vapor Presure | 5.03E-08mmHg at 25°C |
| Appearance | White crystalline powder |
| Color | Off-white |
| Merck | 13,2714 |
| BRN | 615509 |
| pKa | 1.46±0.41(Predicted) |
| Storage Condition | APPROX 4°C |
| Refractive Index | 1.6000 (estimate) |
| MDL | MFCD00055514 |
| Physical and Chemical Properties | Pure white crystals. m.p.167.5 -169 °c, vapor pressure 2.1 x 10-7PA (20 °c). Solubility at 25 ° C: Chloroform 210g/L, cyclohexanol 210g/L, benzene 15g/L, ethanol 45g/L, hexane 15g/L, water 171mg/L. In the acid, alkali or neutral conditions can be hydrolyzed, light, thermal stability. |
| Use | It is a selective absorption-conducting herbicide, suitable for corn, pea, broad bean and other crop fields, to control a variety of grass weeds and broad-leaved weeds |
Fortrol - Risk and Safety
| Risk Codes | R22 - Harmful if swallowed R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R39/23/24/25 - R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R36 - Irritating to the eyes R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R11 - Highly Flammable R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S37 - Wear suitable gloves. S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37 - Wear suitable protective clothing and gloves. S36 - Wear suitable protective clothing. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S16 - Keep away from sources of ignition. |
| UN IDs | UN 2588/2811 |
| WGK Germany | 3 |
| RTECS | UG1490000 |
| Hazard Class | 6.1(b) |
| Packing Group | III |
| Toxicity | LD50 in rats, mice (mg/kg): 182, 380 orally (Chapman) |
Fortrol - Introduction
It is stable to light and heat, and can be hydrolyzed in neutral, slightly acidic or slightly alkaline media.
Last Update：2022-10-16 17:14:58
Fortrol - Reference Information
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| toxicity | acute oral LD50182 in rats ~ 288 mg/kg, 380 mg/kg in mice; Acute percutaneous LD501200mg/kg in rats. The acute inhalation of LC50 in rats was 2.46mg/L, the non-effective dose in chronic feeding test was 12 mg/kg in rats and 25 mg/kg in dogs. No carcinogenic, teratogenic and mutagenic effects. There was no abnormality in the three-generation reproduction test and neurotoxicity test. Low toxicity to birds. The LD50 of quail is 400~500 mg/kg, and the LD50 of wild duck is> 2000 mg/kg. The toxicity to fish is: trout LC50 is 5mg/L, catfish LC5010mg/L, grass shrimp LC50 is 56mg/L. |
| use | triazine selective systemic conduction herbicides. It is suitable for corn, peas, broad beans, potatoes, sugarcane, cotton and other crops to control a variety of gramineous weeds and broadleaf weeds. The dosage is 1~3kg/hm2. It can be mixed with hormone herbicides. It can control broadleaf weeds that are difficult to remove in wheat fields. It can also be used in sorghum, peanuts and other crops. Use before and after buds. This product was put into production by Shell Chemical Company in 1971. It is a selective systemic conduction herbicide and is suitable for corn, peas, broad beans, potatoes, sugar cane, cotton and other crop fields to control various gramineous weeds and broadleaf weeds. It is a selective absorption conduction herbicide, suitable for corn, peas, broad beans and other crop fields to control a variety of gramineous weeds and broadleaf weeds Cyanatine was put into production by Shell Chemical Company in 1971. It is a selective absorption conduction herbicide, suitable for corn, peas, broad beans, potatoes, sugar cane, cotton and other crop fields to control a variety of gramineous weeds and broadleaf weeds. |
| production method | after cooling the acetone suspension of cyanuric chloride and amino isobutyronitrile to 0 ℃, adding 50% sodium hydroxide solution under stirring, adding ethylamine and sodium hydroxide after the reaction mixture is neutral to obtain cyanopine. first, hydroxy isobutyronitrile is reacted with ammonia to prepare amino isobutyronitrile, then the acetone suspension of cyanuric chloride and amino isobutyronitrile are cooled to 0 ℃, and 50% sodium hydroxide solution is added under stirring. After the reaction mixture is neutral, ethylamine and sodium hydroxide are added to prepare cyanopine. |
| category | pesticide |
| toxicity classification | highly toxic |
| acute toxicity | oral-rat LD50: 149 mg/kg; Oral-mouse LD50: 380 mg/kg |
| flammability hazard characteristics | Combustion produces toxic nitrogen oxides and chloride gases |
| storage and transportation characteristics | warehouse ventilation and low temperature drying; separate from food raw materials storage and transportation |
| fire extinguishing agent | dry powder, foam, sand |
| occupational standard | TLV-TWA 5 mg/m3 |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-09 21:04:16
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