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DMH

5,5-Dimethylhydantoin

CAS: 77-71-4

Molecular Formula: C5H8N2O2

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DMH - Names and Identifiers

Name 5,5-Dimethylhydantoin
Synonyms T10
DMH
t10[qr]
dmh[qr]
nsc8652
dantoindmh
dmhydantoin
DM Hydantoin
Dimethylhydantoin
5,5-Dimethylhydantoin
5,5-Dimethylhydrantoin
5,5-Dimethyl hydantoin
Hydantoin, 5,5-dimethyl-
5,5-Dimethyl-2,4-imidazolidinedione
5,5-dimethylimidazolidine-2,4-dione
CAS 77-71-4
EINECS 201-051-3
InChI InChI=1/C5H8N2O2/c1-5(2)3(8)6-4(9)7-5/h1-2H3,(H2,6,7,8,9)

DMH - Physico-chemical Properties

Molecular FormulaC5H8N2O2
Molar Mass128.13
Density1.2864 (rough estimate)
Melting Point174-177 °C (lit.)
Boling Point237.54°C (rough estimate)
Flash Point193°C
Water Solubilitysoluble
Solubility H2O: 0.1g/mL hot, clear
AppearanceWhite crystal
ColorWhite to off-white
BRN2827
pKapKa 8.1 (Uncertain)
Storage ConditionSealed in dry,Room Temperature
Refractive Index1.4730 (estimate)
MDLMFCD00005266
Physical and Chemical PropertiesWhite prismatic crystals or crystalline powders. Melting Point 175 °c. Soluble in water, hexanol, ethyl acetate, dimethyl ether, slightly soluble in isoacetone, acetone, methyl ethyl ketone, insoluble in aliphatic hydrocarbons, trichloroethylene. Odorless, sublimable, acidic.
UseMainly used as disinfectant, epoxy resin and amino acid raw materials

DMH - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk Codes36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS22 - Do not breathe dust.
S24/25 - Avoid contact with skin and eyes.
S36/37 - Wear suitable protective clothing and gloves.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany2
RTECSMU0977000
TSCAYes
HS Code29332100
ToxicityLD50 oral in rabbit: 12660mg/kg

DMH - Reference Information

NIST chemical information information provided by: webbook.nist.gov (external link)
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
Introduction 5, 5-dimethylhydantoin is an important organic synthesis intermediate with a wide range of uses, it is a heterocyclic compound with a certain rigid skeleton. A range of valuable derivatives can be prepared by substitution reactions. Such as: dibromohydantoin, dichlorohydantoin and other widely used in organic synthesis, medicine, plastics, food, cosmetics, pesticides and other production areas.
Application 5, 5-dimethylhydantoin, also known as 5, 5-dimethylhydantoin, DMH, is a wide range of uses of organic synthesis intermediates, is a rigid heterocyclic compounds, can be prepared by substitution reaction of a series of valuable derivatives, such as: dibromohydantoin, dichlorohydantoin and other widely used in medicine, fine Chemicals in the production of pesticides, plastics and cosmetics.
preparation a. Add 600-800 parts of ammonium bicarbonate and 500-700 parts of acetone cyanohydrin to water and stir to fully dissolve, sealed when heated to 10 ℃; B. 30-50 parts of ammonia gas is introduced into the material prepared by Step a, and heated slowly to 50-65 ℃ for 1-2 hours, and stirring; c, the material prepared by Step B is heated to 75~85 ℃, the air is drawn for 30~50 minutes, and then cooled to room temperature and filtered to obtain crude dimethyl hydantoin and mother liquor; d. 950~1150 parts of crude dimethyl hydantoin prepared by Step c is put into a mixture of 150~300 parts of water and 700~900 parts of mother liquor, after heating to 80~98 ° C., 3~8 parts of activated carbon is added, decolorization is carried out for 20~40 minutes, the activated carbon is removed by filtration, and then crystallization is cooled, centrifugal filtration and drying are carried out to obtain a dimethyl hydantoin finished product.
uses for amino acid synthesis, but also as a special epoxy resin and water-soluble resin, fungicides, preservatives, etc. Its derivatives such as 1, 3-dichloro-5, 5-dimethylhydantoin can be used as chlorinating agent, Disinfection bactericide, 3-hydroxymethyl-5, 5-dimethylhydantoin is useful as a formaldehyde agent, a preservative, and the like.
mainly used as disinfectant, epoxy resin and amino acid raw materials
production method is obtained by reacting acetone cyanohydrin ([75-86-5]) with an aqueous ammonium carbonate solution at 50-80 °c.
toxic substance data information provided by: pubchem.ncbi.nlm.nih.gov (external link)
Last Update:2024-04-09 21:21:28
DMH
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Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: 5,5-Dimethylhydantoin Request for quotation
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Tel: 0086-551-65418684
Email: sales@tnjchem.com
     info@tnjchem.com
Mobile: 0086 189 4982 3763
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Shanghai Yuanye Bio-Technology Co., Ltd.
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DMH
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