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Chloromethoxyethane

chloromethyl ethyl ether

CAS: 3188-13-4

Molecular Formula: C3H7ClO

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Chloromethoxyethane - Names and Identifiers

Name chloromethyl ethyl ether
Synonyms ClCH2OC2H5
Chloromethoxyethane
chloromethoxy-ethane
(chloromethoxy)-ethan
(chloromethoxy)ethane
chloromethylethylester
1-(Chloromethoxy)ethane
chloromethyl ethyl ether
Ether, chloromethyl ethyl
Ethane, (chloromethoxy)-
CAS 3188-13-4
EINECS 221-687-5
InChI InChI=1/C3H7ClO/c1-2-5-3-4/h2-3H2,1H3

Chloromethoxyethane - Physico-chemical Properties

Molecular FormulaC3H7ClO
Molar Mass94.54
Density1.019g/mLat 25°C(lit.)
Melting Point-104°C
Boling Point82°C(lit.)
Flash Point67°F
Vapor Presure85.6mmHg at 25°C
AppearanceLiquid
Specific Gravity1.019
ColorClear colorless to pale yellow
Storage Condition0-6°C
Refractive Indexn20/D 1.404(lit.)
Physical and Chemical PropertiesDensity 1.019
boiling point 82°C
refractive index 1.4-1.405
flash point 19°C
UseFor Organic synthesis

Chloromethoxyethane - Risk and Safety

Risk CodesR11 - Highly Flammable
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36 - Irritating to the eyes
R40 - Limited evidence of a carcinogenic effect
Safety DescriptionS16 - Keep away from sources of ignition.
S36/37 - Wear suitable protective clothing and gloves.
S9 - Keep container in a well-ventilated place.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S29 - Do not empty into drains.
UN IDsUN 2354 3/PG 2
WGK Germany3
HS Code29091990
Hazard Class6.1(a)
Packing GroupI

Chloromethoxyethane - Reference Information

NIST chemical information Information provided by: webbook.nist.gov (external link)
EPA chemical information Information provided by: ofmpub.epa.gov (external link)
application chloromethyl ether is an intermediate of acetochlor. Acetochlor is an excellent herbicide, which is widely used for weeding in corn, cotton, peanut and soybean fields.
preparation a new synthesis process of acetochlor intermediate chloromethyl ether, which includes the following steps:(1) putting ammonium chloride into an ether distillation kettle containing etherified base acid, mixing evenly, adding concentrated sulfuric acid dropwise and stirring at a constant speed, and generating hydrogen chloride gas under the action of concentrated sulfuric acid;(2) The hydrogen chloride gas obtained in step (1) is introduced into the etherification reactor containing paraformaldehyde and ethanol, and the temperature is kept below 70 ℃. When a large amount of hydrogen chloride gas that has not participated in the reaction comes out in the etherification reactor, the reaction ends.
use chloromethyl ether is an intermediate of herbicide acetochlor.
for organic synthesis
production method its preparation method is to add ethanol and trioxymethylene into a reaction kettle, pass in hydrogen chloride gas under stirring, control the reaction temperature, pass in a certain amount of hydrogen chloride, sample and analyze, reach the end point of the reaction, stand for stratification, lower layer is hydrochloric acid, upper layer is chloromethyl ethyl ether, which can be distilled and purified. 3C2H5OH (CH2O)3 3HCl→3ClCH2OC2H5 3H2O
category flammable liquid
explosive hazard characteristics explosion in case of fire
flammability hazard characteristics flammable; toxic chloride fumes from the fire site
storage and transportation characteristics warehouse is low temperature, ventilated and dry; Fire prevention; Vibration prevention
fire extinguishing agent carbon dioxide, foam, dry powder
toxic substance data information provided by: pubchem.ncbi.nlm.nih.gov (external link)
Last Update:2024-04-10 22:29:15
Chloromethoxyethane
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Product Name: chloromethyl ethyl ether Request for quotation
CAS: 3188-13-4
Tel: 0513-66814854
Email: pules.cn@gmail.com
Mobile: +86-17551318830
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View History
Chloromethoxyethane
1-Decylcyclohexane
C. I. Pigment Red 104 (77605)
MES-SDS BUFFER 20X
2-[2-(2-methylpropoxy)ethoxy]-ethano
Acid Orange 67
Ferrous
YM201636
MOLYBDOCENE DICHLORIDE
2123-20-8
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