ALLYLTRIBUTYLSTANNANE
allyltributylstannane
CAS: 24850-33-7
Molecular Formula: C15H32Sn
ALLYLTRIBUTYLSTANNANE - Names and Identifiers
| Name | allyltributylstannane |
| Synonyms | Allyltributyltin ALLYLTRIBUTYLTIN Allytri-N-Butyltin ALLYLTRI-N-BUTYLTIN Allyltri-n-butyltin ALLYLTRIBUTYLTIN(IV) Allyl tri-n-butyl tin allyltributylstannane ALLYLTRIBUTYLSTANNANE Allyltri-n-butylstannane TRIBUTYL-2-PROPENYLSTANNANE 3-(Tributylstannyl)prop-1-ene Tri-n-butyl-2-propenylstannane Stannane, tributyl-2-propenyl- tributyl(prop-2-en-1-yl)stannane |
| CAS | 24850-33-7 |
| EINECS | 246-494-3 |
| InChI | InChI=1/3C4H9.C3H5.Sn/c3*1-3-4-2;1-3-2;/h3*1,3-4H2,2H3;3H,1-2H2;/rC15H32Sn/c1-5-9-13-16(12-8-4,14-10-6-2)15-11-7-3/h8H,4-7,9-15H2,1-3H3 |
| InChIKey | YLGRTLMDMVAFNI-UHFFFAOYSA-N |
ALLYLTRIBUTYLSTANNANE - Physico-chemical Properties
| Molecular Formula | C15H32Sn |
| Molar Mass | 331.12 |
| Density | 1.068g/mLat 25°C(lit.) |
| Melting Point | 134-135 °C |
| Boling Point | 88-92°C0.2mm Hg(lit.) |
| Flash Point | >230°F |
| Water Solubility | Immiscible with water. |
| Vapor Presure | 0.00098mmHg at 25°C |
| Appearance | Liquid |
| Specific Gravity | 1.068 |
| Color | Clear colorless |
| Exposure Limit | ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
| BRN | 3588340 |
| Storage Condition | 2-8°C |
| Sensitive | Air Sensitive |
| Refractive Index | n20/D 1.486(lit.) |
ALLYLTRIBUTYLSTANNANE - Risk and Safety
| Risk Codes | R21 - Harmful in contact with skin R25 - Toxic if swallowed R36/38 - Irritating to eyes and skin. R48/23/25 - R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. |
| Safety Description | S35 - This material and its container must be disposed of in a safe way. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S28 - After contact with skin, wash immediately with plenty of soap-suds. S27 - Take off immediately all contaminated clothing. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| UN IDs | UN 2788 6.1/PG 2 |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 13 |
| TSCA | No |
| HS Code | 29319019 |
| Hazard Class | 6.1 |
| Packing Group | II |
ALLYLTRIBUTYLSTANNANE - Reference Information
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| uses | allylation reagent for aldehydes. the catalysts for this reaction are chiral Lewis acids 1,2 and ytterbium trifluoromethanesulfonate (III)(product number 430595). 3 Under the catalysis of tetrakis (triphenylphosphine) palladium (0)(product number 216666), coupling reaction occurs with iodoquinone 4 and allyl acetate. 5,67 is used for the high-efficiency allylation reaction of aldehydes and trichloro-1, 3, 5-triazene to produce high allyl alcohol. |
Last Update：2024-04-10 22:29:15
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