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976-56-7

Diethyl 3,5-di-tert-butyl-4-hydroxybenzyl phosphate

CAS: 976-56-7

Molecular Formula: C19H33O5P

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976-56-7 - Names and Identifiers

Name Diethyl 3,5-di-tert-butyl-4-hydroxybenzyl phosphate
Synonyms Irganox1222
Diethyl 3,5-di-tert-butyl-4-hydroxybenzyl phosphate
Diethyl3,5-di-tert-buty-4-hydroxy-ben-zylphosphonate
Phosphonicacid,[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]-,diethylester
CAS 976-56-7
EINECS 213-551-9

976-56-7 - Physico-chemical Properties

Molecular FormulaC19H33O5P
Molar Mass356.44
Density1.046±0.06 g/cm3(Predicted)
Melting Point122 °C
Boling Point417.0±33.0 °C(Predicted)
Storage ConditionRoom Temprature
MDLMFCD00227871
Physical and Chemical PropertiesWhite or yellowish crystalline powder. Melting point 159-161 °c. The number of grams dissolved in 0.6 of the following solvents at 20 ° C. Is: acetone 27, methanol 62, benzene 33, chloroform 50, n-hexane 0.01, ethyl acetate 20, water.
UseThe product is a phosphorus-containing hindered phenol antioxidant and has good extraction resistance. Especially suitable for polyester anti-aging. It is generally added prior to polycondensation as it is a catalyst for polycondensation of the polyester. Can also be used for polyamide as a light stabilizer, and has anti-Oxygen effect. There is a synergistic effect in combination with an ultraviolet absorber. The general dosage of 0.3-1.0. The product is also useful as a stabilizer for dimethyl terephthalate in storage and transport. The toxicity of the product is low. Mice oral LD50>5000mg/kg.

976-56-7 - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant

976-56-7 - Introduction

Open Data Unverified Data

Antioxidant 1222, chemically known as 2,2'-Methylenebis(4-methyl-6-tert-butylphenol), is a commonly used phenolic antioxidant. It is primarily employed in polymer materials (such as plastics, rubber, synthetic fibers, etc.) to prevent degradation and aging caused by oxidation during processing and use.

Key Features:

  1. Antioxidant Properties: Effectively scavenges free radicals, inhibiting oxidation reactions and extending the material's lifespan.
  2. Thermal Stability: Maintains excellent antioxidant performance even under high-temperature conditions.
  3. Compatibility: Exhibits good compatibility with various polymer materials, ensuring easy dispersion.
  4. Low Volatility: Minimizes evaporation during processing and use, providing long-lasting antioxidant effects.

Applications:

  • Plastics Industry: Used for oxidation resistance in polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), and other plastics.
  • Rubber Industry: Prevents aging in natural and synthetic rubber.
  • Synthetic Fibers: Applied in polyester, nylon, and other fibers for oxidation protection.
  • Lubricants and Fuels: Added as an additive to prevent oxidation and deterioration of oils and fuels.

Precautions:

  • The appropriate dosage should be determined based on the specific material's processing conditions and application environment.
  • Store in a cool, dry, and well-ventilated area, avoiding high temperatures, moisture, and direct sunlight.
Last Update:2025-04-25 16:29:41

976-56-7 - Synthesis of antioxidant bis (3, 5-di-tert-butyl-4-hydroxybenzylphosphonic acid monoethyl ester) calcium salt

from VIP Journal Professional Edition

Author:

Native , LV , Qian Jianhua

Abstract:

The antioxidant calcium salt was synthesized from domestic 2, 6-di-tert-butylphenol with paraformaldehyde, triethyl phosphite, hydrated sodium hydroxide and calcium chloride in four steps. The structure of each step product is dominated by NMR, IR and elemental analysis.

Key words:

Antioxidant; Calcium salt of BIS (3, 5-di-tert-butyl-4-hydroxybenzylphosphonic acid monoethyl ester); Triethyl phosphite; calcium chloride; Synthesis

DOI:

CNKI:SUN:JXSY.0.1996-03-005

cited:

1

year:

1996

Last Update:2024-01-02 23:10:35

976-56-7 - Synthesis of diethyl (3, 5-di-tert-butyl-4-hydroxy)-benzylphosphonate

from

VIP web Author:

Who Yao Ruo

Abstract:

In this paper, 2, 6-di-tert-butylphenol is reacted with formaldehyde and dimethylamine to form N, n-dimethyl-3, 5-, di-tert-butyl-4-hydroxybenzylamine by Mannich reaction, the product is then reacted with a diethyl phosphonate to give the title compound. Its IR and ~ 1HNMR are consistent with the structure. The product is a hindered antioxidant, suitable for polyester fiber, polypropylene fiber and polyvinyl chloride fiber.

Key words:

Antioxidant diethyl phosphate synthesis Antioxidant

year:

1990

Last Update:2023-08-16 22:05:47
976-56-7
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