944451-30-3

944451-30-3 - Names and Identifiers

Name	Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride
Synonyms	[RUCL(P-CYMENE)((R)-DM-SEGPHOS)]CL (R)-RuCl[(p-cyMene)(DM-SEGPHOS)]Cl [RuCl(p-cymene)((R)-dm-segphos[R])]Cl [RuCl(p-cymene)((R)-dm-segphos(regR))]Cl [RuCl(p-cymene)((R)-dm-segphos(regR))]Cl [RuCl(p-cymene)((R)-dm-segphos)]Cl Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-dm-segphos(R))]Cl
CAS	944451-30-3

944451-30-3 - Physico-chemical Properties

Molecular Formula	C56H58Cl2O4P2Ru
Molar Mass	1028.980842
Melting Point	>100°C
Water Solubility	Insoluble in water
Appearance	Powder
Color	orange to brown
Storage Condition	2-8°C
Sensitive	air sensitive

944451-30-3 - Risk and Safety

WGK Germany

944451-30-3 - Introduction

Chloro{(R)-( )-5,5 '-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride is an organometallic compound with the formula [RuCl(p-cymene)][(R)-binap], where p-cymene represents p-toluene,(R)-binap is R-( )-5,5 '-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole.

Nature:
- Chloro{(R)-( )-5,5 '-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) is chloride a solid, white crystal at room temperature.
-It is soluble in organic solvents such as toluene, dichloromethane and ethanol.
-It is an asymmetric complex that can transfer chiral information to other molecules in the reaction.

Use:
- Chloro{(R)-( )-5,5 '-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride are commonly used as chiral catalysts to participate in a variety of organic reactions, such as hydrogenation, oxidation, synthesis, etc.
-It has an important application in asymmetric synthesis, which can control stereochemistry and obtain a single chiral product.

Preparation Method:
- Chloro{(R)-( )-5,5 '-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene) The preparation of ruthenium(II) chloride is usually achieved by ligand exchange reaction, and [RuCl2(p-cymene)2] is reacted with (R)-binap to produce the target compound.

Safety Information:
- Chloro{(R)-( )-5,5 '-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene) Safety information chloride by ruthenium(II) should follow the general practice for chemicals.
-It may be harmful to the environment and needs to be operated and handled under suitable facilities.
-During use and storage, avoid contact with open flames and oxygen to prevent the risk of fire or explosion.
-Detailed safety information can be obtained through the safety data sheet provided by the chemical supplier.

Last Update：2024-04-10 22:29:15