71423-54-6
(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS: 71423-54-6
Molecular Formula: C36H38BF4O2P2Rh
71423-54-6 - Names and Identifiers
71423-54-6 - Physico-chemical Properties
| Molecular Formula | C36H38BF4O2P2Rh |
| Molar Mass | 754.35 |
| Appearance | Powder |
| Color | orange |
| Sensitive | air sensitive |
71423-54-6 - Risk and Safety
| Safety Description | S22 - Do not breathe dust. S24/25 - Avoid contact with skin and eyes. |
| HS Code | 28439000 |
71423-54-6 - Introduction
(S,S)-( )-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is an organo-rhodium complex. The following is a description of its nature, use, formulation and safety information:
Nature:
- (S,S)-( )-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a light-sensitive orange solid.
-It is stable in the air, but it will decompose in water and acidic conditions.
Use:
- (S,S)-( )-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used to catalyze asymmetric reactions, especially asymmetric hydrogenation reactions and asymmetric
Alkaline oxidation reaction.
-It is often used as a catalyst in organic synthesis, which can effectively catalyze the asymmetric hydrogenation of olefins, asymmetric hydrogenation, asymmetric carbonyl reduction and other reactions.
Preparation Method:
- (S,S)-( )-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate are generally prepared by a ligand exchange reaction.
-In the preparation process, first (S,S)-( )-1,2-bis (diphenylphosphino)ethane and 1,5-cyclooctadiene are reacted with chlorotetrafluoroborate ether solution to obtain the corresponding Chloride complex. Then, under alkaline conditions
(o-methoxyphenyl) triphenylphosphine was added to cause ligand exchange reaction with the chloride complex to obtain the target product.
Safety Information:
- (S,S)-( )-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate require certain safety precautions during handling and storage.
-It should avoid contact with strong oxidants, strong acids and strong bases to avoid dangerous reactions.
-Wear appropriate personal protective equipment such as protective gloves and safety glasses during handling.
-Waste should be disposed of in accordance with local chemical waste disposal regulations.
Nature:
- (S,S)-( )-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a light-sensitive orange solid.
-It is stable in the air, but it will decompose in water and acidic conditions.
Use:
- (S,S)-( )-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used to catalyze asymmetric reactions, especially asymmetric hydrogenation reactions and asymmetric
Alkaline oxidation reaction.
-It is often used as a catalyst in organic synthesis, which can effectively catalyze the asymmetric hydrogenation of olefins, asymmetric hydrogenation, asymmetric carbonyl reduction and other reactions.
Preparation Method:
- (S,S)-( )-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate are generally prepared by a ligand exchange reaction.
-In the preparation process, first (S,S)-( )-1,2-bis (diphenylphosphino)ethane and 1,5-cyclooctadiene are reacted with chlorotetrafluoroborate ether solution to obtain the corresponding Chloride complex. Then, under alkaline conditions
(o-methoxyphenyl) triphenylphosphine was added to cause ligand exchange reaction with the chloride complex to obtain the target product.
Safety Information:
- (S,S)-( )-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate require certain safety precautions during handling and storage.
-It should avoid contact with strong oxidants, strong acids and strong bases to avoid dangerous reactions.
-Wear appropriate personal protective equipment such as protective gloves and safety glasses during handling.
-Waste should be disposed of in accordance with local chemical waste disposal regulations.
Last Update：2024-04-09 02:00:47
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Product Name: (S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Request for quotationCAS: 71423-54-6
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Product Name: (S,S)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Visit Supplier Webpage Request for quotationCAS: 71423-54-6
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
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Product Name: [Rh(COD)(S,S-DIPAMP)] BF4 Visit Supplier Webpage Request for quotationCAS: 71423-54-6
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
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Product Name: (S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Visit Supplier Webpage Request for quotation
CAS: 71423-54-6
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CAS: 71423-54-6
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
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