380230-02-4
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
CAS: 380230-02-4
Molecular Formula: C36H30NO2P
380230-02-4 - Names and Identifiers
| Name | (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) |
| Synonyms | (S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine |
| CAS | 380230-02-4 |
| InChIKey | LKZPDRCMCSBQFN-UIOOFZCWSA-N |
380230-02-4 - Physico-chemical Properties
| Molecular Formula | C36H30NO2P |
| Molar Mass | 539.6 |
| Melting Point | 88-89°C |
| Boling Point | 710.7±63.0 °C(Predicted) |
| Specific Rotation(α) | +13.1° (c 1.01, CHCl3) |
| Appearance | Powder |
| Color | off-white |
| pKa | -0.57±0.20(Predicted) |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
| Sensitive | moisture sensitive |
| Use | Chiral phosphoramidite ligands for copper-catalyzed high enantioselective conjugate addition reactions that allow the addition of dialkyl zinc to various Michael receptors. 1,2,3 can also be used for diethylzinc-mediated palladium-catalyzed polarity reversal allylation. |
380230-02-4 - Risk and Safety
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| WGK Germany | 3 |
380230-02-4 - Reference Information
| Applications | chiral phosphoramidite ligands for copper-catalyzed Highly Enantioselective conjugate addition reactions, this reaction can add dialkyl zinc to a variety of Michael receptors. 1,2,3 can also be used for diethylzinc-mediated palladium-catalyzed polarity reversal allylation reactions. |
Last Update：2024-04-09 02:00:02
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View History
380230-02-4
C.I. Vat Orange 1 (6CI,8CI)
Diazo Red RC, AR
4-Methyl-4-pentenal
2-Fluoro-5-methylnicotinaldehyde
3-硬脂酰基噻吩
正丙基磷酸二乙酯
甲基丙烯酸镁
114661-63-1
2-Methoxyphenyl bromide
C.I. Vat Orange 1 (6CI,8CI)
Diazo Red RC, AR
4-Methyl-4-pentenal
2-Fluoro-5-methylnicotinaldehyde
3-硬脂酰基噻吩
正丙基磷酸二乙酯
甲基丙烯酸镁
114661-63-1
2-Methoxyphenyl bromide