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3-Diethylaminophenol

3-Hydroxy-N,N-diethylaniline

CAS: 91-68-9

Molecular Formula: C10H15NO

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3-Diethylaminophenol - Names and Identifiers

Name 3-Hydroxy-N,N-diethylaniline
Synonyms DEMAP
diethylaminophenol
3-DIETHYLAMINOPHENOL
M-DIETHYLAMINOPHENOL
3-diethylaminophenol
3-(diethylamino)-pheno
m-(diethylamino)-pheno
m-Hydroxydiethylaniline
m-N,N-Diethylaminophenol
N,N-Diethyl-3-aminophenol
DIETHYL META AMINO PHENOL
N,N-DIETHYL-M-AMINO-PHENOL
3-(N,N'-DIETHYLAMINO)PHENOL
3-Hydroxy-N,N-diethylaniline
N,N DIETHYL META AMINO PHENOL
3-DIETHYLAMINOPHENOL GRANULATED
1-(DIETHYLAMINO)-3-HYDROXYBENZENE
CAS 91-68-9
EINECS 202-090-9
InChI InChI=1/C10H15NO/c1-3-11(4-2)9-6-5-7-10(12)8-9/h5-8,12H,3-4H2,1-2H3

3-Diethylaminophenol - Physico-chemical Properties

Molecular FormulaC10H15NO
Molar Mass165.23
Density1.0203 (rough estimate)
Melting Point69-72 °C (lit.)
Boling Point170 °C/15 mmHg (lit.)
Flash Point141 °C
Water Solubility<0.1 g/100 mL at 20.5 ºC
Solubility 4.087g/L in organic solvents at 20 ℃
Vapor Presure0.345Pa at 25℃
AppearanceWhite crystal
ColorGray-brown to rose or red
BRN908212
pKa10.08±0.10(Predicted)
Storage ConditionInert atmosphere,Room Temperature
Refractive Index1.4820 (estimate)
MDLMFCD00002265
Physical and Chemical PropertiesAppearance White to Rose Bengal crystals
physical and chemical properties melting point 78°C, boiling point 276-280°C. Soluble in water, ethanol, ether and alkali, slightly soluble in petroleum hydrocarbons.
UseUsed as rose essence, acid PEACH RED, basic rose red and other dye intermediates

3-Diethylaminophenol - Risk and Safety

Risk CodesR25 - Toxic if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S22 - Do not breathe dust.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
S24/25 - Avoid contact with skin and eyes.
UN IDsUN 2512 6.1/PG 3
WGK Germany2
RTECSSL0550500
HS Code29222900

3-Diethylaminophenol - Nature

Open Data Verified Data

white or rose-colored crystals. The melting point of 78 deg C, boiling point of 276~280 deg C. Soluble in water, ethanol, ether and alkali, slightly soluble in petroleum hydrocarbons. This product is irritating.

Last Update:2025-06-10 22:55:16

3-Diethylaminophenol - Preparation Method

Open Data Verified Data
  1. iron powder reduction method: firstly, M-nitrobenzenesulfonic acid sodium salt is reduced to M-aminobenzenesulfonic acid sodium salt with iron powder, and then reacted with ethyl chloride, and obtained by alkylation, alkali fusion and acid analysis. Each production of 1T of the product raw material consumption: M-aminobenzenesulfonic acid sodium (industrial) 1860kg, ethyl chloride (industrial) lOOOkg, caustic soda (caustic) 2000kg, potassium hydroxide 800kg.
  2. alkylation of M-aminophenol.

Last Update:2022-01-01 10:52:33

3-Diethylaminophenol - Introduction

Slightly soluble in water, soluble in alcohol, ether, ketone, ester, carbon disulfide, aromatic hydrocarbon and sodium hydroxide solution, insoluble in petroleum ether.
Last Update:2022-10-16 17:30:04

3-Diethylaminophenol - Application

Open Data Verified Data

This product can be used in the dye industry; It is also an important intermediate of a variety of fluorescent whitening agents, especially coumarin type fluorescent whitening agents.

Last Update:2025-08-19 16:24:40

3-Diethylaminophenol - Safety

Open Data Verified Data

highly toxic. Such as inhalation, ingestion, skin contact absorption is fatal. Wear appropriate protective gloves, clothing and glasses. The combustion of irritant, corrosive and (or) toxic gases. In iron drum packing 70kg/barrel.

Last Update:2025-06-10 22:55:16

3-Diethylaminophenol - Reference Information

LogP0.929 at 23℃
NIST chemical information information provided by: webbook.nist.gov (external link)
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
purpose This product is an intermediate of rose essence, acid pink, basic rose red and other dyes, and is also used in other organic synthesis.
It is used as intermediate of rose essence, acid pink, basic rose red and other dyes
production method sodium M-nitrobenzenesulfonate is reduced to sodium M-aminobenzenesulfonate with iron powder, then alkylated with Chloroethane, and then alkali melted with sodium hydroxide, final acidification gave the finished product.
Last Update:2024-04-09 15:16:53
3-Diethylaminophenol
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