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1,5-dihydroxyanthraquinone

1,5-dihydroxyanthraquinone

CAS: 117-12-4

Molecular Formula: C14H8O4

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1,5-dihydroxyanthraquinone - Names and Identifiers

Name 1,5-dihydroxyanthraquinone
Synonyms Anthrarufin
ANTHRARUFIN
1,5-dihydroxyanthraquinone
1,5-dihydroxyanthracene-9,10-dione
9,10-Anthracenedione, 1,5-dihydroxy-
CAS 117-12-4
EINECS 204-175-6
InChI InChI=1/C14H8O4/c15-9-5-1-3-7-11(9)14(18)8-4-2-6-10(16)12(8)13(7)17/h1-6,15-16H

1,5-dihydroxyanthraquinone - Physico-chemical Properties

Molecular FormulaC14H8O4
Molar Mass240.21
Density1.54g/cm3
Melting Point268-273℃
Boling Point452.7°C at 760 mmHg
Flash Point241.7°C
Vapor Presure8.21E-09mmHg at 25°C
Vapor Density8.3 (vs air)
pKa6.42±0.20(Predicted)
Storage Condition-20°C Freezer
Refractive Index1.732
MDLMFCD00001210
Physical and Chemical PropertiesThe chemical properties precipitate light yellow flake crystals from acetic acid. Melting point 280 ℃. Sublimation can be achieved at 120 ℃. Soluble in benzene and nitrobenzene, slightly soluble in ethanol, acetic acid and ether, soluble in potassium hydroxide solution is red, insoluble in sodium carbonate solution and ammonia, soluble in concentrated sulfuric acid is fluorescent red.
UseFor synthetic dyes

1,5-dihydroxyanthraquinone - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk Codes36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS22 - Do not breathe dust.
S24/25 - Avoid contact with skin and eyes.
WGK Germany3
RTECSCB6630000
TSCAYes
HS Code29146990

1,5-dihydroxyanthraquinone - Upstream Downstream Industry

Raw MaterialsAluminium chloride hexahydrate
Anthracene
MERCURY(II) SULFATE
1,4-Anthracenedione, 2,3-dihydro-5,9,10-trihydroxy-
1,8-Dihydroxyanthraquinone
Downstream ProductsDisperse Blue BGL
CI 63010
CI 63010
1,2,5-TRIHYDROXYANTHRAQUINONE
Solvent Blue 74

1,5-dihydroxyanthraquinone - Nature

Merck 14,689
BRN 1881718
EPA chemical information Anthrarufin (117-12-4)
Last Update:2024-04-10 22:29:15

1,5-dihydroxyanthraquinone - Uses and synthesis methods

use

1,1, 5-dihydroxyanthraquinone is an intermediate of disperse dyes and acid dyes. 1,5-dihydroxyanthraquinone -2,6-disulfonic acid can be obtained from the sulfonation of 1,5-dihydroxyanthraquinone. Continue to nitrification, reduction, addition translocation, and desulphurization of this intermediate to obtain dispersion Blue S-BGL.

2, for synthetic dyes

production method

There are anthraquinone sulfonation and benzoic acid sulfonation. (1) 1,5-anthraquinone disulfonic acid and 1,8-anthraquinone disulfonic acid were obtained by sulfonation with anthraquinone as raw material and mercury sulfate as positioning agent. 1, 5-anthraquinone disulfonic acid by alkali fusion, acidification to obtain 1, 5-dihydroxyanthraquinone. (2) Benzoic acid is used as raw material, obtained by sulfonation, alkali melting, acidification, condensation and closed loop. This method does not use mercury catalyst to remove mercury damage, but the closed-loop one-step yield is only 40%, and a large amount of aluminum trichloride is consumed. This method consumes higher, also brings other aspects of pollution, and high production costs.

Last Update:2024-04-09 21:04:16
1,5-dihydroxyanthraquinone
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Shanghai Macklin Biochemical Co., Ltd
Featured ProductsSpot supply
Product Name: Anthrarufin Visit Supplier Webpage Request for quotation
CAS: 117-12-4
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328 Click to send a QQ message
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Product Name: 1,5-dihydroxyanthraquinone Request for quotation
CAS: 117-12-4
Tel: 021-60556179
Email: 18721521379@163.com
Mobile: +86-18721521379
Wechat: 18721521379
Jiangsu Pules Biotechnology Co.,Ltd.
Spot supply
Product Name: 1,5-dihydroxyanthraquinone Request for quotation
CAS: 117-12-4
Tel: 0513-66814854
Email: pules.cn@gmail.com
Mobile: +86-17551318830
JIANGSU BSECHEM CHEMICAL TECHNOLOGY CO., LTD.
Spot supply
Product Name: 1,5-dihydroxyanthraquinone Request for quotation
CAS: 117-12-4
Tel: +86-17505207175
Email: 3787852685@qq.com
Mobile: +86-17505207175
QQ: 3787852685 Click to send a QQ message
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Nantong Reform Petro-Chemical CO., LTD.
Spot supply
Product Name: 1,5-dihydroxyanthraquinone Request for quotation
CAS: 117-12-4
Tel: +86-13776910623
Email: r@reformchem.com­
Mobile: +86-13776910623
QQ: 3785839865 Click to send a QQ messageSend QQ message
Wechat: chemical6666 
Shanghai Amole Biotechnology Co., Ltd.
Spot supply
Product Name: 1,5-dihydroxyanthraquinone Request for quotation
CAS: 117-12-4
Tel: 400-968-2212
Email: 3623107365@qq.com
Mobile: 18916960931
QQ: 3623107365 Click to send a QQ message
Wechat: 18916960931
SHANGHAI ACMEC BIOCHEMICAL TECHNOLOGY CO., LTD.
Spot supply
Product Name: 1,5-Dihydroxyanthracene-9,10-dione Visit Supplier Webpage Request for quotation
CAS: 117-12-4
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922 Click to send a QQ message
Wechat: 18621343501
WhatsApp: +86-18621343501
MedChemExpress (MCE)
Spot supply
Product Name: Anthrarufin Visit Supplier Webpage Request for quotation
CAS: 117-12-4
Tel: 609-228-6898
Email: sales@medchemexpress.com
     tech@medchemexpress.com
Mobile: 609-228-6898
Shanghai Yuanye Bio-Technology Co., Ltd.
Product Name: Anthrarufin Visit Supplier Webpage Request for quotation
CAS: 117-12-4
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409 Click to send a QQ message
View History
1,5-dihydroxyanthraquinone
N-BOC-氨基-(3-噻吩基)乙酸
γ-Oxo-benzenebutanoic acid
METHYL 3-BROMOTHIOPHENE-2-CARBOXYLATE
Raw Materials for 1,5-dihydroxyanthraquinone
Aluminium chloride hexahydrate
Anthracene
MERCURY(II) SULFATE
1,4-Anthracenedione, 2,3-dihydro-5,9,10-trihydroxy-
1,8-Dihydroxyanthraquinone
Downstream Products for 1,5-dihydroxyanthraquinone
Disperse Blue BGL
CI 63010
CI 63010
1,2,5-TRIHYDROXYANTHRAQUINONE
Solvent Blue 74
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