(R)-RuCL

(R)-RuCL - Names and Identifiers

Name	(R)-RuCl[p-cymene)(H8-BINAP)]Cl (R)-RuCl[p-cymene)(H8-BINAP)]Cl
Synonyms	(R)-RuCL [p-cymene)(H8-BINAP)]CL (R)-RuCl[p-cymene)(H8-BINAP)]Cl (R)-RuCl[p-cymene)(H8-BINAP)]Cl Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)r [(R)-(+)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) dichloride Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl
CAS	944451-26-7

(R)-RuCL - Physico-chemical Properties

Molecular Formula	C54H52Cl2P2Ru
Molar Mass	934.93
Melting Point	>100°C
Appearance	Powder
Color	pale yellow
Storage Condition	2-8°C
Sensitive	air sensitive

(R)-RuCL - Risk and Safety

WGK Germany

(R)-RuCL - Introduction

(R)-RuCl[p-cymene)(H8-BINAP)]Cl is a metal-organic compound whose main component is ruthenium (Ru), the ligand is p-cyclodiisopropylbenzylgluconol (p-cymene) and a chiral phosphine ligand (H8-BINAP). The following are some of the properties, uses, preparation and safety information of the compound:

Nature:
-Appearance: colorless crystal
-Solubility: Soluble in non-polar organic solvents, such as chloroform, dimethylformamide, etc.
-Melting point: about 200-203°C
-Molecular formula: C27H33Cl2P2Ru

Use:
(R)-RuCl[p-cymene)(H8-BINAP)]Cl is commonly used in organic synthesis reactions, especially asymmetric catalytic reactions. It can be used as a chiral catalyst for asymmetric hydrogenation, olefin hydrogenation, and carbonyl reduction of asymmetric unsaturated compounds.

Preparation Method:
The preparation of (R)-RuCl[p-cymene)(H8-BINAP)]Cl is usually achieved by a ligand exchange reaction. First, it is necessary to synthesize the RuCl2(p-cymene)2 complex, and then carry out the ligand exchange reaction with the H8-BINAP ligand to obtain the final product.

Safety Information:
Limited safety information for (R)-RuCl[p-cymene)(H8-BINAP)]Cl. In the case of any chemical, appropriate laboratory safety measures should be taken when using and handling it. Inhalation, contact with skin and eyes should be avoided. Wear appropriate personal protective equipment during use and ensure that the operation is carried out in a well-ventilated place. If inhaled or touched, seek medical help.

Last Update：2024-04-10 22:29:15