Name | Tetrakis(triphenylphosphine)nickel |
Synonyms | Tetrakis(triphenylphosphine)nickel NICKEL-TETRAKIS(TRIPHENYLPHOSPHINE) Tetrakis-(triphenylphosphino)-nickel TETRAKIS(TRIPHENYLPHOSPHINE)NICKEL(O) TETRAKIS(TRIPHENYLPHOSPHINE)NICKEL(0) Nickel, tetrakis(triphenylphosphine)-, (T-4)- |
CAS | 15133-82-1 |
InChI | InChI=1/4C18H15P.Ni/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H |
Molecular Formula | C72H60NiP4 |
Molar Mass | 1107.84 |
Melting Point | 123-128°C |
Boling Point | 360°C at 760 mmHg |
Flash Point | 181.7°C |
Water Solubility | Insoluble in water. |
Vapor Presure | 4.74E-05mmHg at 25°C |
Appearance | Fine Powder |
Color | Rust-brown to brown |
Exposure Limit | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
Storage Condition | Inert atmosphere,Room Temperature |
Sensitive | Air Sensitive |
Physical and Chemical Properties | Storage Conditions: 2-8℃ sensitivity: Air Sensitive WGK Germany:3 |
Risk Codes | R40 - Limited evidence of a carcinogenic effect R43 - May cause sensitization by skin contact R11 - Highly Flammable |
Safety Description | S36/37 - Wear suitable protective clothing and gloves. S36 - Wear suitable protective clothing. S22 - Do not breathe dust. |
UN IDs | UN 1325 4.1/PG 2 |
WGK Germany | 3 |
FLUKA BRAND F CODES | 1-10 |
HS Code | 29319090 |
Hazard Class | 4.2 |
Packing Group | II |
Use | tetrakis (triphenylphosphine) nickel is usually slightly harmful to water, do not expose undiluted or bulk products to groundwater, watercourses or sewage systems, and do not discharge materials into the surrounding environment without government permission. It can be used as a ligand of a complex catalyst, and is used for a carbonyl synthesis reaction, a phosphorus-containing vixic reagent Intermediate, a reducing agent, a flame retardant of a graft copolymer, an olefin carbonylation catalyst, a crosslinking agent of an epoxy resin, and the like. |