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Cobalt (Ⅲ) oxide

Cobaltic oxide

CAS: 1308-04-9

Molecular Formula: Co2O3

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Cobalt (Ⅲ) oxide - Names and Identifiers

Name Cobaltic oxide
Synonyms C.I. 77323
Cobaltic oxide
Cabalt trioxide
cobalt(iii)oxide
Cobalt (Ⅲ) oxide
dicobalttrioxide
Cobalt(III) oxide
Cobalt sesquioxide
BLACKCOBALTICOXIDE
Cobalt oxide (Co2O3)
Cobalt(Iii) Oxide Black
Cobaltic oxide monohydrate
COBALT(III) OXIDE BLACK, PURE
COBALT(III) OXIDE R. G., FOR THE DETERMI NATION OF SULFUR
CAS 1308-04-9
EINECS 215-156-7

Cobalt (Ⅲ) oxide - Physico-chemical Properties

Molecular FormulaCo2O3
Molar Mass165.86
Density6.11g/mLat 25°C(lit.)
Melting Point895°C (dec.)(lit.)
Water Solubilityinsoluble H2O; soluble conc acids [HAW93]
AppearanceBlack powder
Storage ConditionInert atmosphere,Room Temperature
Physical and Chemical PropertiesColorless monoclinic crystal.

melting point 86.5 ℃

relative density 1.69(17 ℃)

solubility: soluble in water, acid and alkali, insoluble in alcohol. The aqueous solution was acidic.
UseUsed as analytical reagents, oxidants and catalysts, but also for the preparation of cobalt and nickel-free cobalt salts

Cobalt (Ⅲ) oxide - Risk and Safety

Hazard SymbolsXn - Harmful
Harmful
Risk CodesR36/37/38 - Irritating to eyes, respiratory system and skin.
R40 - Limited evidence of a carcinogenic effect
R43 - May cause sensitization by skin contact
R22 - Harmful if swallowed
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S36/37 - Wear suitable protective clothing and gloves.
WGK Germany1
RTECSGG2500000

Cobalt (Ⅲ) oxide - Upstream Downstream Industry

Raw MaterialsCobalt
Ammonium Bicarbonate
Nitric acid
Downstream ProductsAluminum hydroxide
Sulfuric acid, aluminum ammonium salt (2:1:1)
Potassium dichromate
Fosetyl-aluminum
Lead(II) chromate
Aluminium stearate

Cobalt (Ⅲ) oxide - Nature

Open Data Verified Data

A black-gray hexagonal or orthorhombic powder. Melting point 895 C (decomposition);d 5. 18. Dissolved in hot hydrochloric acid release chlorine; Dissolved in hot dilute sulfuric acid release oxygen. Insoluble in water, ethanol. Insoluble in water, ethanol, soluble in acid. It can be reduced to cobalt oxide by hydrogen at 125 ℃, cobalt oxide at 200 ℃, and cobalt metal at 250 ℃.

Last Update:2024-01-02 23:10:35

Cobalt (Ⅲ) oxide - Preparation Method

Open Data Verified Data

nickel-free analytically pure cobalt hydroxide was placed in a porcelain dish and burned in an electric furnace at 350 to 370 ° C. For 4 to 5 hours. Nickel-free analytical pure cobalt trioxide is available. Alternatively, nickel-free basic cobalt carbonate is placed in a porcelain dish and burned in an electric furnace at 350-370 ° C. For 4-5H to obtain cobalt trioxide.

Last Update:2022-01-01 09:01:45

Cobalt (Ⅲ) oxide - Use

Open Data Verified Data

used as an analytical reagent, an oxidizing agent, a catalyst, and the preparation of cobalt and nickel-free cobalt salts.

Last Update:2022-01-01 09:01:45

Cobalt (Ⅲ) oxide - Safety

Open Data Verified Data

It has a stimulating effect on the eyes, respiratory system and gastrointestinal tract. Inhalation can cause acute poisoning, the emergence of bronchial asthma. The maximum allowable concentration is 0.5 mg/m3. Staff should be protected. Store in a cool, ventilated warehouse. Keep the container sealed. It shall be stored separately from oxidants, acids and edible chemical raw materials.

Last Update:2022-01-01 09:01:46

Cobalt (Ⅲ) oxide - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
toxicity inhalation will cause acute poisoning and bronchial asthma. The maximum allowable concentration is 0.5 mg/m3. During operation, an anti-virus mask should be worn to prevent aerosol from damaging respiratory organs. Wear dust-proof overalls and protective gloves.
Uses Used as pigments and glazes and magnetic materials, can be used to make cobalt and nickel-free cobalt salts, and also used as oxidants and catalysts, etc.
Used as analytical reagents, oxidants and catalysts, and also used to make cobalt and nickel-free cobalt salts
used in pigments, glazes and magnetic materials. It can also be used to produce cobalt and nickel-free cobalt salts. Also used as oxidant and catalyst, etc.
production method cobalt carbonate burning method uses cobalt carbonate as raw material, places it in an electric furnace, and burns at 350~370 ℃ for 4~5h under the condition of isolated air or slightly reducing atmosphere to produce high cobalt oxide. Its 2 CoCO3[△]→ Co2O3 CO ↑ CO2 ↑
category toxic substances
toxicity classification low toxicity
acute toxicity abdominal cavity-rat LD50: 5000 mg/kg; Subcutaneous-mouse LD50: 2060 mg/kg
flammability hazard characteristics non-combustible; toxic cobalt-containing smoke from the fire site
storage and transportation characteristics warehouse low temperature, ventilation, drying
fire extinguishing agent water, carbon dioxide, dry powder, sand
occupational standard TWA 0.05 mg (cobalt)/m3
Last Update:2024-04-10 22:29:15
Cobalt (Ⅲ) oxide
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CAS: 1308-04-9
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CAS: 1308-04-9
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View History
Cobalt (Ⅲ) oxide
2-(4-苯基-1,2,3-噻二唑-5-基)异二氢吲哚啉-1,3-二酮
4-氯-5-碘-6-(三氟甲基)嘧啶-2-胺
N-(叔丁氧羰基)-D-2-(4-氯苯基)甘氨酸
2-(吡啶-4'-基)-6-溴吡啶
2-氟-4-硝基苯乙酸乙酯
N-(3-氰苯基)吡咯
Raw Materials for Cobalt (Ⅲ) oxide
Cobalt
Ammonium Bicarbonate
Nitric acid
Downstream Products for Cobalt (Ⅲ) oxide
Aluminum hydroxide
Sulfuric acid, aluminum ammonium salt (2:1:1)
Potassium dichromate
Fosetyl-aluminum
Lead(II) chromate
Aluminium stearate
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