Name | lithium diisopropylamide |
Synonyms | LDA LDA THF COMPLEX ithium diisopropyL DIISOPROPYLAMINOLITHIUM LITHIUM DIISOPROPYLAMIDE LITHIUM DIISOPROPYLAMINE lithium diisopropylamide Lithium diisopropylazanide Lithium diisopropylamide solution lithium bis(1-methylethyl)azanide LITHIUM DIISOPROPYLAMIDE THF COMPLEX |
CAS | 4111-54-0 |
EINECS | 223-893-0 |
InChI | InChI=1/C6H15N.Li/c1-5(2)7-6(3)4;/h5-7H,1-4H3;/q;+1 |
Molecular Formula | C6H16LiN |
Molar Mass | 109.14 |
Density | 0.864 g/mL at 25 °C (lit.) |
Melting Point | decomposes [MER06] |
Boling Point | 65°C |
Flash Point | 91°F |
Water Solubility | decomposes |
Vapor Density | >1 (vs air) |
Appearance | liquid |
Color | brown |
Merck | 14,3196 |
BRN | 3655042 |
Storage Condition | 2-8°C |
Sensitive | Air & Moisture Sensitive |
Risk Codes | R14 - Reacts violently with water R17 - Spontaneously flammable in air R34 - Causes burns R67 - Vapors may cause drowsiness and dizziness R65 - Harmful: May cause lung damage if swallowed R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R35 - Causes severe burns R19 - May form explosive peroxides R15 - Contact with water liberates extremely flammable gases R11 - Highly Flammable R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R14/15 - R10 - Flammable R40 - Limited evidence of a carcinogenic effect R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R62 - Possible risk of impaired fertility R63 - Possible risk of harm to the unborn child R37 - Irritating to the respiratory system R48/20 - |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S62 - If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. S8 - Keep container dry. S16 - Keep away from sources of ignition. S23 - Do not breathe vapour. S33 - Take precautionary measures against static discharges. S27 - Take off immediately all contaminated clothing. |
UN IDs | UN 3399 4.3/PG 2 |
WGK Germany | 3 |
FLUKA BRAND F CODES | 1-10 |
TSCA | Yes |
HS Code | 29211990 |
Hazard Class | 4.2 |
Packing Group | I |