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2,5-二溴-3,4-二硝基噻吩

2,5-Dibromo-3,4-dinitrothiophene

CAS: 52431-30-8

Molecular Formula: C4Br2N2O4S

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  5. 2,5-二溴-3,4-二硝基噻吩

2,5-二溴-3,4-二硝基噻吩 - Names and Identifiers

Name 2,5-Dibromo-3,4-dinitrothiophene
Synonyms S1073
NSC 84661
AKOS 92299
DibroMo-3,4-dinitrothio
2,5-Dibromo-3,4-dinitrthiphene
2,5-DIBROMO-3,4-DINITROTHIOPHENE
2,5-Dibromo-3,4-dinitrothiophene
CAS 52431-30-8
EINECS 676-535-4
InChI InChI=1/C4Br2N2O4S/c5-3-1(7(9)10)2(8(11)12)4(6)13-3
InChIKey AHGHPBPARMANQD-UHFFFAOYSA-N

2,5-二溴-3,4-二硝基噻吩 - Physico-chemical Properties

Molecular FormulaC4Br2N2O4S
Molar Mass331.93
Density2.459±0.06 g/cm3(Predicted)
Melting Point137°C
Boling Point341.2±37.0 °C(Predicted)
Flash Point160.2°C
Water SolubilityInsoluble in water.
Solubility Acetone, Methanol
Vapor Presure0.000161mmHg at 25°C
AppearanceSolid
ColorLight Orange
BRN218219
Storage ConditionKeep in dark place,Sealed in dry,Room Temperature
Refractive Index1.716
MDLMFCD00015537

2,5-二溴-3,4-二硝基噻吩 - Risk and Safety

Hazard SymbolsXn - Harmful
Harmful
Risk CodesR36/37/38 - Irritating to eyes, respiratory system and skin.
R22 - Harmful if swallowed
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
S37 - Wear suitable gloves.
WGK Germany3
HS Code29349990

2,5-二溴-3,4-二硝基噻吩 - Reference Information

Use 2,5-dibromo-3, 4-dinitrothiophene is an organic intermediate. 2, 5-dibromo-3, 4-dinitrothiophene can be used to prepare 2, 5-dibromo-3, 4-diaminothiophene, 2, 5-dibromo-3, 4-diaminothiophene is an antibacterial chain extender.
preparation the first step can be obtained by one-step nitration of 2, 5-dibromothiophene: 5mL concentrated sulfuric acid and 5mL fuming sulfuric acid are mixed evenly in a three-mouth flask, then 1mL 2,5-dibromothiophene is added dropwise into the mixed acid, stirred for 30min, cooled down in an ice bath, controlled the temperature below 20 ℃, and the stirring speed is 100r/min;
step 2: add 3mL of concentrated nitric acid dropwise to the system under stirring and stir for 5 hours. the reaction process requires ice bath to cool down, control the temperature below 30 ℃, and stir at a speed of 100r /min;
Step 3: Pour the reaction product into 300g ice cubes and stir until the ice cubes are completely melted; Then vacuum suction filtration is carried out, and the obtained solid is fully washed and filtered with water. Then recrystallized with methanol and the solid is precipitated, the solution was removed by suction filtration, and 2, 5-dibromo-3, 4-dinitrothiophene was obtained after drying.
Last Update:2024-04-09 21:04:16
2,5-二溴-3,4-二硝基噻吩
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