中文名 | 西红花苷II |
英文名 | CrocinII |
别名 | 西红花苷-2 西红花苷II 西红花苷II(对照品) 西红花苷II(标准品) CROCIN Ⅱ 西红花苷Ⅱ (2E,4E,6E,8E,10E,12E,14E)-1-((((2S,3R,4S,5S,6R)-3,4,5-三羟基-6-(((2R,3R,4S ,5S,6R)-3,4,5-三羟基-6-(羟甲基)四氢-2H-吡喃-2-基)氧基)甲基)四氢-2H-吡喃-2-基)16-((2S,3R ,4S,5S,6R)-3,4,5-三羟基-6-(羟甲基)四氢-2H-吡喃-2-基)2,6,11,15-四甲基十六烷基-2,4,6,8,10 ,12,14-庚二烯酸酯 |
英文别名 | CrocinII Crocin 2 Tricrocin Crocin II glucopyranosyl ester Crocetingentiobiosylglucosyl ester 8,8'-Diapo-ψ,ψ-carotenedioic acid, β-D- glucopyranosyl 6-O-β-D-glucopyranosyl-β-D- 1-[(2E,4E,6E,8E,10E,12E,14E)-b-D-glucopyranosyl 2,6,11,15-tetramethyl-2,4,6,8,10,12,14-hexadecaheptaenedioate] 6-O-b-D-glucopyranosyl-b-D-Glucopyranose 1-[(2E,4E,6E,8E,10E,12E,14E)-B-D-Glucopyranosyl 2,6,11,15-Tetramethyl-2,4,6,8,10,12,14-Hexadecaheptaenedioate] 6-O-B-D-Glucopyranosyl-B-D-Glucopyranose beta-D-Glucopyranose 6-O-beta-D-glucopyranosyl-1-[(2E,4E,6E,8E,10E,12E,14E)-beta-D-glucopyranosyl 2,6,11,15-tetramethyl-2,4,6,8,10,12,14-hexadecaheptaenedioate] (2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl (2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-({[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl]oxy}methyl)tetrahydro-2H-pyran-2-yl (2E,4E,6E,8E,10E,12E,14E)-2,6,11,15-tetramethylhexadeca-2,4,6,8,10,12,14-heptaenedioate (non-preferred name) |
CAS | 55750-84-0 |
化学式 | C38H54O19 |
分子量 | 814.82 |
InChI | InChI=1/C38H54O19/c1-18(11-7-13-20(3)34(50)56-37-32(48)29(45)26(42)23(16-40)54-37)9-5-6-10-19(2)12-8-14-21(4)35(51)57-38-33(49)30(46)27(43)24(55-38)17-52-36-31(47)28(44)25(41)22(15-39)53-36/h5-14,22-33,36-49H,15-17H2,1-4H3/b6-5+,11-7+,12-8+,18-9+,19-10+,20-13+,21-14+/t22-,23-,24-,25-,26-,27-,28+,29+,30+,31-,32-,33-,36-,37+,38+/m1/s1 |
密度 | 1.47 |
熔点 | 208-210°C |
沸点 | 1032.1±65.0 °C(Predicted) |
闪点 | 309.764°C |
蒸汽压 | 0mmHg at 25°C |
溶解度 | 易溶于水、甲醇等,难溶于非极性溶剂。 |
折射率 | 1.636 |
酸度系数 | 12.50±0.70(Predicted) |
存储条件 | under inert gas (nitrogen or Argon) at 2-8°C |
敏感性 | Easily absorbing moisture |
外观 | 深红色结晶粉末 |
物化性质 | 红色结晶粉末,可溶于甲醇、乙醇、DMSO等有机溶剂,来源于西红花。 |
MDL号 | MFCD11111454 |
海关编号 | 29389090 |
参考资料 展开查看 | 1. 戴智慧 黄士文 倪穗 等. HPLC法测定浙江慈溪水稻田栽培的西红花中西红花苷Ⅰ、Ⅱ含量的研究[J]. 中国野生植物资源 2016 35(002):14-18. 2. 王萌萌 徐步斌 周斌 等. HPLC法测定西红花不同部位中西红花苷-Ⅰ和苷-Ⅱ[J]. 中成药 2019 041(005):1102-1105. 3. 谢典, 王萌萌, 徐步斌,等. 江西产西红花中西红花苷-I和苷-II的静态分析[J]. 江西科技师范大学学报, 2019, No.190(06):69-71. 4. 彭平, 张蓓, 杜菁,等. 基于天然麝香-牛黄和4个植物药味的安宫牛黄丸特征图谱质量表征研究[J]. 中草药, 2019(14). 5. 田瑞华, 彭平, 刘希,等. 栀子药材的质量表征与产地的关联性研究[J]. 世界科学技术:中医药现代化, 2019(5):882-891. 6. 曹虹虹, 严维花, 郭爽,等. 基于多成分测定及指纹图谱评价不同产地栀子质量[J]. 中国中药杂志, 2019, v.44(18):196-203. 7. 曹虹虹, 严维花, 郭爽,等. 栀子姜炙工艺及姜炙前后化学成分变化研究[J]. 中国中药杂志, 2019(24). 8. 朱颖洁,杨亚洁,李群和,邹盈,罗自生.栀子果油的生物活性成分及抗氧化活性评价[J].现代食品科技,2021,37(02):103-113+102. 9. [IF=2.896] Lu Wang et al."Rapid assay for testing superoxide anion radical scavenging activities to natural pigments by ultra-high performance liquid chromatography-diode-array detection method."Anal Methods-Uk. 2015 Feb;7(4):1535-1542 10. [IF=4.411] Chunnan Li et al."Screening of the Hepatotoxic Components in Fructus Gardeniae and Their Effects on Rat Liver BRL-3A Cells."Molecules. 2019 Jan;24(21):3920 11. [IF=2.447] Jianrong Chen et al."Anti‑inflammatory activities of Gardenia jasminoides extracts in retinal pigment epithelial cells and zebrafish embryos."Exp Ther Med. 2021 Jul;22(1):1-9 12. [IF=3.935] Jie Li et al."Quality consistency evaluation between dispensing granules and traditional decoction of Gardeniae Fructus based on chemical similarity and bioequivalence."J Pharmaceut Biomed. 2022 May;213:114708 13. [IF=7.514] Hao Huang et al."Integrated natural deep eutectic solvent and pulse-ultrasonication for efficient extraction of crocins from gardenia fruits (Gardenia jasminoides Ellis) and its bioactivities."Food Chem. 2022 Jun;380:132216 14. [IF=2.343] Ye Xiao et al."Comprehensive profiling of phytochemicals in the fruits of Gardenia jasminoides Ellis and its variety using liquid chromatography coupled with electrospray ionization quadrupole time-of-flight mass spectrometry."Journal of Natural Medicines. |
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